Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes
Publication type: Journal Article
Publication date: 2019-02-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Bis(indenyl)-rhodium and -iridium complexes [(η5-indenyl)M(η5-C9H2R5)]PF6 (2a: M = Rh, R = H; 2b: M = Ir, R = H; 3: M = Rh, R = Me) were synthesized by reactions of iodides [(η5-indenyl)MI2]n (1a,b) with indenes in the presence of AgPF6. The structures of 2aSbF6 and 2bPF6 were determined by X-ray diffraction. They have fully eclipsed geometry, in which the bridgehead carbon atoms of the indenyl ligands are arranged close to each other. Experimental and DFT calculation data showed that the strength of the M−indenyl bond in the bis(indenyl) compounds decreases in the following row: Ir > Co > Rh.
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Nelyubina Y. V. et al. Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes // Journal of Organometallic Chemistry. 2019. Vol. 880. pp. 312-316.
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Kharitonov V. B., Loginov D. A., Nelyubina Y. V., Kosenko I. Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes // Journal of Organometallic Chemistry. 2019. Vol. 880. pp. 312-316.
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TY - JOUR
DO - 10.1016/j.jorganchem.2018.11.027
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X18308428
TI - Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes
T2 - Journal of Organometallic Chemistry
AU - Kharitonov, Vladimir B.
AU - Loginov, Dmitry A.
AU - Nelyubina, Yulia V.
AU - Kosenko, I.
PY - 2019
DA - 2019/02/01
PB - Elsevier
SP - 312-316
VL - 880
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2019_Nelyubina,
author = {Vladimir B. Kharitonov and Dmitry A. Loginov and Yulia V. Nelyubina and I. Kosenko},
title = {Synthesis and structure of bis(indenyl)-rhodium and -iridium complexes},
journal = {Journal of Organometallic Chemistry},
year = {2019},
volume = {880},
publisher = {Elsevier},
month = {feb},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X18308428},
pages = {312--316},
doi = {10.1016/j.jorganchem.2018.11.027}
}