Generation of ferrocenylvinyl cation CpFeC5 H4 –C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts
Olga A Kizas
1
,
Ivan S Chaschin
1
,
Ivan A Godovikov
1
,
Fedor Dolgushin
1
,
D. Yu. Antonov
1
,
Lev N Nikitin
1
,
Тип публикации: Journal Article
Дата публикации: 2017-07-29
scimago Q3
wos Q3
БС1
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Краткое описание
Cation CpFeC5H4–C+=CH2 was obtained by protonation of FcC CH with Nafion superacid in DMF or scCO2 and characterized by NMR spectroscopy. The protonation in the presence of SMe2 or PPh3 affords new onium derivatives, which were isolated as the tetrafluoroborate salts.
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Kizas O. A. et al. Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 368-370.
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Kizas O. A., Chaschin I. S., Godovikov I. A., Dolgushin F., Antonov D. Y., Nikitin L. N., Khokhlov A. R. Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts // Mendeleev Communications. 2017. Vol. 27. No. 4. pp. 368-370.
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TY - JOUR
DO - 10.1016/j.mencom.2017.07.016
UR - https://doi.org/10.1016/j.mencom.2017.07.016
TI - Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts
T2 - Mendeleev Communications
AU - Kizas, Olga A
AU - Chaschin, Ivan S
AU - Godovikov, Ivan A
AU - Dolgushin, Fedor
AU - Antonov, D. Yu.
AU - Nikitin, Lev N
AU - Khokhlov, Alexei R.
PY - 2017
DA - 2017/07/29
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 368-370
IS - 4
VL - 27
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2017_Kizas,
author = {Olga A Kizas and Ivan S Chaschin and Ivan A Godovikov and Fedor Dolgushin and D. Yu. Antonov and Lev N Nikitin and Alexei R. Khokhlov},
title = {Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts},
journal = {Mendeleev Communications},
year = {2017},
volume = {27},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://doi.org/10.1016/j.mencom.2017.07.016},
number = {4},
pages = {368--370},
doi = {10.1016/j.mencom.2017.07.016}
}
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Kizas, Olga A., et al. “Generation of ferrocenylvinyl cation CpFeC5H4–C+=CH2 by protonation of ferrocenylacetylene with Nafion and its reactions with SMe2 and PPh3 in scCO2 giving onium salts.” Mendeleev Communications, vol. 27, no. 4, Jul. 2017, pp. 368-370. https://doi.org/10.1016/j.mencom.2017.07.016.