Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
Publication type: Journal Article
Publication date: 2019-09-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
A reaction of [Cu(MeCN)4]BF4 with PzH (3,5-dimethylpyrazole) and BINAP [2,20-bis(diphenylphosphino)-1,10-binaphthyl] leads to the formation of mononuclear CuI complex [Cu(PzH)(BINAP)]BF4 containing the molecule of nondeprotonated pyrazole and one BINAP ligand with two phosphorus atoms chelating the metal. This complex exhibits a bright phosphorescence originating from the 3(M+L)LCT state at room temperature. At 77 K, the emission is splitted into two components: 3(M+L)LCT and 3LC transitions.
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Citations from 2024:
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Titov A. A. et al. Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 570-572.
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Titov A. A., Filippov O. A., Smol’yakov A. F., Averin A. A., Shubina E. S. Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties // Mendeleev Communications. 2019. Vol. 29. No. 5. pp. 570-572.
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TY - JOUR
DO - 10.1016/j.mencom.2019.09.031
UR - https://doi.org/10.1016/j.mencom.2019.09.031
TI - Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties
T2 - Mendeleev Communications
AU - Titov, Aleksei A
AU - Filippov, Oleg A.
AU - Smol’yakov, Alexander F.
AU - Averin, Alexey A
AU - Shubina, Elena S.
PY - 2019
DA - 2019/09/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 570-572
IS - 5
VL - 29
SN - 0959-9436
SN - 1364-551X
ER -
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@article{2019_Titov,
author = {Aleksei A Titov and Oleg A. Filippov and Alexander F. Smol’yakov and Alexey A Averin and Elena S. Shubina},
title = {Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties},
journal = {Mendeleev Communications},
year = {2019},
volume = {29},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {sep},
url = {https://doi.org/10.1016/j.mencom.2019.09.031},
number = {5},
pages = {570--572},
doi = {10.1016/j.mencom.2019.09.031}
}
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MLA
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Titov, Aleksei A., et al. “Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties.” Mendeleev Communications, vol. 29, no. 5, Sep. 2019, pp. 570-572. https://doi.org/10.1016/j.mencom.2019.09.031.