Dehydrogenation of amine–boranes catalyzed by a PC s p 3 P
Vladislava A Kirkina
1
,
Gleb A Silantyev
1
,
Natalia V Belkova
1
,
Elena Y. Osipova
1
,
Oleg A. Filippov
1
,
Dmitri Gelman
2
,
Publication type: Journal Article
Publication date: 2020-05-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
Dibenzobarrelene-based PC s p 3 P pincer iridium complex bearing dangling CH2OH groups, ( ( PC s p 3 P CH 2 OH ) IrH ( Cl ) , catalyzes the dehydrogenation of amine–boranes at the reaction rate changing counter intuitively in the order: Me2NH·BH3 > > ButNH2·BH3 > NH3·BH3. The spectral (IR and NMR) data and DFT/M06 calculations have revealed that the binding of amine–boranes to the dangling OH group leads to an additional stabilization of the Ir···OH bond, thus hampering the dehydrogenation reaction, whereas the amine–borane coordination to iridium entails a fac- to mer-transformation of the complex and initiates the catalytic H2 evolution.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
|
|
|
Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
2 publications, 33.33%
|
|
|
Chemical Communications
1 publication, 16.67%
|
|
|
ChemCatChem
1 publication, 16.67%
|
|
|
Mendeleev Communications
1 publication, 16.67%
|
|
|
Organometallics
1 publication, 16.67%
|
|
|
1
2
|
Publishers
|
1
2
|
|
|
Pleiades Publishing
2 publications, 33.33%
|
|
|
Royal Society of Chemistry (RSC)
1 publication, 16.67%
|
|
|
Wiley
1 publication, 16.67%
|
|
|
Elsevier
1 publication, 16.67%
|
|
|
American Chemical Society (ACS)
1 publication, 16.67%
|
|
|
1
2
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
6
Total citations:
6
Citations from 2024:
3
(50%)
The most citing journal
Citations in journal:
2
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Kirkina V. A. et al. Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 276-278.
GOST all authors (up to 50)
Copy
Kirkina V. A., Silantyev G. A., Belkova N. V., Osipova E. Y., Filippov O. A., Gelman D., Shubina E. S. Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex // Mendeleev Communications. 2020. Vol. 30. No. 3. pp. 276-278.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.05.004
UR - https://doi.org/10.1016/j.mencom.2020.05.004
TI - Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex
T2 - Mendeleev Communications
AU - Kirkina, Vladislava A
AU - Silantyev, Gleb A
AU - Belkova, Natalia V
AU - Osipova, Elena Y.
AU - Filippov, Oleg A.
AU - Gelman, Dmitri
AU - Shubina, Elena S.
PY - 2020
DA - 2020/05/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 276-278
IS - 3
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Kirkina,
author = {Vladislava A Kirkina and Gleb A Silantyev and Natalia V Belkova and Elena Y. Osipova and Oleg A. Filippov and Dmitri Gelman and Elena S. Shubina},
title = {Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {may},
url = {https://doi.org/10.1016/j.mencom.2020.05.004},
number = {3},
pages = {276--278},
doi = {10.1016/j.mencom.2020.05.004}
}
Cite this
MLA
Copy
Kirkina, Vladislava A., et al. “Dehydrogenation of amine–boranes catalyzed by a PCsp3P pincer iridium complex.” Mendeleev Communications, vol. 30, no. 3, May. 2020, pp. 276-278. https://doi.org/10.1016/j.mencom.2020.05.004.
Profiles