Mendeleev Communications
,  volume 30 ,  issue 4 ,  pages 494-495

Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative

Publication type: Journal Article
Publication date: 2020-07-01
scimago Q3
wos Q3
SJR: 0.305
CiteScore: 3.0
Impact factor: 1.7
ISSN: 09599436, 1364551X
General Chemistry
Abstract
The consecutive alkylation of 9-isopropyl-6-phenyl-9H-purine with methyl 2-diazo-3,3,3-trifluoropropionate and diethyl diazomalonate proceeds at the phenyl substituent firstly via ortho-C–H activation under chelation-assistance of the purine core, followed by classical electrophilic metal carbenoid insertion to the C−H bond of a malonate moiety.
Found 
Found 
2 citations
Nelyubina Yulia
🤝
DSc in Chemistry
506 publications,  7 574 citations,  1 review
h-index: 38
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
Moscow Institute of Physics and Technology
Research interests
Big Data
Catalysis
Machine learning
Metal-organic frameworks
Quantum technologies
Sensors
2 citations
Loginov Dmitry
🥼
DSc in Chemistry
125 publications,  1 792 citations,  36 reviews
h-index: 25
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Catalysis
Coordination Chemistry
Organic Chemistry
Organic synthesis
Organometallic Chemistry
Photonics
2 citations
Osipov Sergey
DSc in Chemistry
138 publications,  2 725 citations,  3 reviews
h-index: 29
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
1 citation
Larionov Vladimir
🥼 🤝
DSc in Chemistry
54 publications,  1 070 citations,  106 reviews
h-index: 18
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Peoples' Friendship University of Russia
Peoples' Friendship University of Russia
Research interests
Asymmetric catalysis
1 citation
Kharitonov Vladimir
23 publications,  252 citations
h-index: 10
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Catalysis
Density functional theory (DFT)
Organic Chemistry
Organometallic Chemistry
1 citation
Chusov Denis
DSc in Chemistry, professor
97 publications,  2 368 citations,  35 reviews
h-index: 24
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Asymmetric metal complex catalysis
Catalysis
Medicinal Chemistry
Organic Chemistry
Total synthesis

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GOST Copy
Vinogradov M. M. et al. Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 494-495.
GOST all authors (up to 50) Copy
Vinogradov M. M., Vorobyeva D. V., Nelyubina Y. V., Osipov S. N., Loginov D. A. Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative // Mendeleev Communications. 2020. Vol. 30. No. 4. pp. 494-495.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/j.mencom.2020.07.029
UR - https://linkinghub.elsevier.com/retrieve/pii/S0959943620302005
TI - Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative
T2 - Mendeleev Communications
AU - Vinogradov, Mikhail M
AU - Vorobyeva, Daria V
AU - Nelyubina, Yulia V.
AU - Osipov, Sergey N.
AU - Loginov, Dmitry A.
PY - 2020
DA - 2020/07/01
PB - OOO Zhurnal "Mendeleevskie Soobshcheniya"
SP - 494-495
IS - 4
VL - 30
SN - 0959-9436
SN - 1364-551X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Vinogradov,
author = {Mikhail M Vinogradov and Daria V Vorobyeva and Yulia V. Nelyubina and Sergey N. Osipov and Dmitry A. Loginov},
title = {Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative},
journal = {Mendeleev Communications},
year = {2020},
volume = {30},
publisher = {OOO Zhurnal "Mendeleevskie Soobshcheniya"},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0959943620302005},
number = {4},
pages = {494--495},
doi = {10.1016/j.mencom.2020.07.029}
}
MLA
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MLA Copy
Vinogradov, Mikhail M., et al. “Unusual multiple insertion of diazo carbonyl compounds into (purin-6-yl)benzene derivative.” Mendeleev Communications, vol. 30, no. 4, Jul. 2020, pp. 494-495. https://linkinghub.elsevier.com/retrieve/pii/S0959943620302005.