Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2
Zhanna Dobrokhotova
1
,
Aleksei Sidorov
1
,
Mikhail Bykov
2
,
Marat Fazylbekov
2
,
Anna Emelina
2
,
Grigory Aleksandrov
1
,
Vladimir Novotortsev
1
,
Pavel S Koroteev
1
,
Тип публикации: Journal Article
Дата публикации: 2011-01-01
scimago Q3
wos Q2
БС2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Abstract Lithium-containing heterometallic complexes with cobalt (Li2Co2(Piv)6(2,4-Lut)2 (2, Piv is the pivalate anion) and Li2Co2(O2CCH2But)6(2,4-Lut)2 (3)) and with nickel (Li2Ni2(Piv)6(DME)2 (4) and Li2Ni2(Piv)6(2,2′-bpy)2 (5)) were synthesized. The structures of the complexes were established by X-ray diffraction. The magnetic properties of complexes 2 and 4 were studied. The thermal behavior of compounds 2, 3, and 5 was investigated. It was shown that the compounds under study can be used as molecular precursors for the synthesis of lithium cobaltate and nickelate.
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Sidorov A. et al. Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2 // Polyhedron. 2011. Vol. 30. No. 1. pp. 132-141.
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Dobrokhotova Z., Sidorov A., Bykov M., Fazylbekov M., Emelina A., Aleksandrov G., Novotortsev V., Kiskin M. A., Koroteev P. S., Bogomyakov A. S., Eremenko I. L. Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2 // Polyhedron. 2011. Vol. 30. No. 1. pp. 132-141.
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TY - JOUR
DO - 10.1016/j.poly.2010.09.040
UR - https://doi.org/10.1016/j.poly.2010.09.040
TI - Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2
T2 - Polyhedron
AU - Dobrokhotova, Zhanna
AU - Sidorov, Aleksei
AU - Bykov, Mikhail
AU - Fazylbekov, Marat
AU - Emelina, Anna
AU - Aleksandrov, Grigory
AU - Novotortsev, Vladimir
AU - Kiskin, Mikhail A.
AU - Koroteev, Pavel S
AU - Bogomyakov, Artem S
AU - Eremenko, Igor L.
PY - 2011
DA - 2011/01/01
PB - Elsevier
SP - 132-141
IS - 1
VL - 30
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2011_Sidorov,
author = {Zhanna Dobrokhotova and Aleksei Sidorov and Mikhail Bykov and Marat Fazylbekov and Anna Emelina and Grigory Aleksandrov and Vladimir Novotortsev and Mikhail A. Kiskin and Pavel S Koroteev and Artem S Bogomyakov and Igor L. Eremenko},
title = {Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2},
journal = {Polyhedron},
year = {2011},
volume = {30},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/j.poly.2010.09.040},
number = {1},
pages = {132--141},
doi = {10.1016/j.poly.2010.09.040}
}
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MLA
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Sidorov, Aleksei, et al. “Synthesis and characterization of Li(I)–M(II) (M=Co, Ni) heterometallic complexes as molecular precursors for LiMO2.” Polyhedron, vol. 30, no. 1, Jan. 2011, pp. 132-141. https://doi.org/10.1016/j.poly.2010.09.040.