Complexation Zn2+ and Co2+/3+ with primary diamines: Synthesis, structure and thermal properties
Publication type: Journal Article
Publication date: 2020-11-01
scimago Q3
wos Q2
SJR: 0.396
CiteScore: 4.9
Impact factor: 2.6
ISSN: 02775387, 18733719
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Abstract New types of polyfunctional molecules formed by Co2+/3+ and Zn2+ ions with various diamines - biogenic 1,4-diaminobutane (dab, putrescine) and 1,1′-binaphthyl-2,2′-diamine (dabn) - have been obtained. The structure of the compounds was determined by single crystal X-ray diffraction analysis. Dab in the binuclear complex [Zn2(piv)2(dab)2(Hdab)2]·4piv·2H2O (1) plays the role of a bridging ligand. The H-binding in 1 promotes the formation of a supramolecular layer which, according to STA data, predetermines the thermal stability up to 100 °C. In the mononuclear complex of cobalt(III), [CoIII(piv)2(dab)2]+Cl− (2), dab is chelated with the metal center. Replacement of dab with dabn leads to solely chelate coordination in complexes of cobalt(II), [Co3(OH)(piv)5(dabn)2]·0.5MeCN (3), and zinc, [Zn(dabn)2(NO3)(MeCN)]·2NO3·0.5MeCN (4).
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Total citations:
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Citations from 2024:
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(25%)
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Lutsenko I. A. et al. Complexation Zn2+ and Co2+/3+ with primary diamines: Synthesis, structure and thermal properties // Polyhedron. 2020. Vol. 190. p. 114764.
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Lutsenko I. A., Kiskin M. A., Nelyubina Y. V., Primakov P. V., Shmelev M. A., Efimov N. N., Babeshkin K. A., Khoroshilov A. V., Sidorov A., Eremenko I. L. Complexation Zn2+ and Co2+/3+ with primary diamines: Synthesis, structure and thermal properties // Polyhedron. 2020. Vol. 190. p. 114764.
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TY - JOUR
DO - 10.1016/j.poly.2020.114764
UR - https://doi.org/10.1016/j.poly.2020.114764
TI - Complexation Zn2+ and Co2+/3+ with primary diamines: Synthesis, structure and thermal properties
T2 - Polyhedron
AU - Lutsenko, Irina A
AU - Kiskin, Mikhail A.
AU - Nelyubina, Yulia V.
AU - Primakov, Petr V
AU - Shmelev, M. A.
AU - Efimov, Nikolay N.
AU - Babeshkin, Konstantin A
AU - Khoroshilov, A. V.
AU - Sidorov, A.V
AU - Eremenko, Igor L.
PY - 2020
DA - 2020/11/01
PB - Elsevier
SP - 114764
VL - 190
SN - 0277-5387
SN - 1873-3719
ER -
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@article{2020_Lutsenko,
author = {Irina A Lutsenko and Mikhail A. Kiskin and Yulia V. Nelyubina and Petr V Primakov and M. A. Shmelev and Nikolay N. Efimov and Konstantin A Babeshkin and A. V. Khoroshilov and A.V Sidorov and Igor L. Eremenko},
title = {Complexation Zn2+ and Co2+/3+ with primary diamines: Synthesis, structure and thermal properties},
journal = {Polyhedron},
year = {2020},
volume = {190},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/j.poly.2020.114764},
pages = {114764},
doi = {10.1016/j.poly.2020.114764}
}