Polyhedron, volume 203, pages 115241

Nickel(II) complexes with 2-Hfur and N-donors: The magnetic effects of the structural variations, thermal properties and antimycobacterial activity against Mycolicibacterium smegmatis

Uvarova Marina A ¹

Eremenko Igor L.

Kiskin Mikhail A

Efimov Nikolay N.

Nelyubina Yulia V.

Lutsenko Irina A

Shmelev Maxim A

Babeshkin Konstantin A

Goloveshkin Alexander S.

Khoroshilov Andrey V

Zueva Ekaterina M

Petrova Maria M ²

Bekker Olga B

Primakov Petr V ³

Lutsenko Irina A ¹

Kiskin Mikhail A. ¹

Nelyubina Yulia V. ³

Babeshkin Konstantin A ¹

Efimov Nikolay N. ¹

Goloveshkin Alexander S. ³

Shmelev M. A. ¹

Khoroshilov A. V. ¹

Zueva Ekaterina M ⁴

Bekker Olga B ⁵

Eremenko Igor L. ¹

Hide authors affiliations Show authors affiliations: 5 affiliations

N.S. Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky Prosp. 31, 119991 GSP-1 Moscow, Russian Federation |

Kazan National Research Technological University, Karl Marx str. 68, 420015 Kazan, Russian Federation |

A.N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Vavilova Str. 28, 119991 Moscow, Russian Federation |

⁴

Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov str. 8, 420088 Kazan, Russian Federation

A.E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center of the Russian Academy of Sciences

Kazan Scientific Center of the Russian Academy of Sciences

⁵

Vavilov Institute of General Genetics, Russian Academy of Sciences, Gubkina, 3, 119333 Moscow, Russian Federation |

Publication type: Journal Article

Publication date: 2021-07-01

Elsevier

Journal: Polyhedron

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Impact factor: 2.6

ISSN: 02775387

DOI: 10.1016/j.poly.2021.115241

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Materials Chemistry

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

Abstract New complexes of nickel(II) with 2-furoic acid (2-Hfur) and different N-donor ligands of the composition [Ni(fur)2(phen)(H2O)2]•H2O (1) (phen = 1,10-phenantroline), [Ni(fur)2(2,2’-bpy)] (2, 2,2’-bpy = 2,2’-bipyridine), [Ni(fur)2(4,4’-bpy)(CH3OH)2]n (3, 4,4’-bpy = 4,4’-bipyridine), [Ni(fur)2(pz)4]•2MeCN (4) (pz = pyrazole) have been synthesized. The structure of the compounds was established by single crystal X-ray diffraction analysis. Complexes 1, 2, and 4 are mononuclear, complex 3 is a 1D coordination polymer. The DC magnetic susceptibility data measured for 2 and 3 are indicative of antiferromagnetic exchange interactions between the metal centers, which proved to be negligibly weak in 2 and more pronounced in 3. A quantum-chemical analysis of intermolecular (for 2) and intra- and interchain (for 3) magnetic exchange pathways confirms these findings, revealing the presence of magnetic chains formed by a network of very weak intermolecular antiferromagnetic exchange interactions in the crystal of 2 and a strengthening of antiferromagnetic exchange coupling in the polymeric chains of 3. Thermal behavior of 1 and 2 was studied by simultaneous thermal analysis (STA). According to PXRD data, the final thermolysis product of complex 2 is metal Ni nanocrystals (d = 14.7(3) nm). Analysis of the results of biological activity of 1–4 in vitro against Mycolicibacterium smegmatis showed a low sensitivity of the mycobacterial wall to Ni2+ cations.

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Citations by journals

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Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya, 7, 36.84% Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya 7 publications, 36.84%
Russian Chemical Bulletin	Russian Chemical Bulletin, 3, 15.79% Russian Chemical Bulletin 3 publications, 15.79%
Polyhedron	Polyhedron, 3, 15.79% Polyhedron 3 publications, 15.79%
RSC Advances	RSC Advances, 1, 5.26% RSC Advances 1 publication, 5.26%
Russian Journal of Inorganic Chemistry	Russian Journal of Inorganic Chemistry, 1, 5.26% Russian Journal of Inorganic Chemistry 1 publication, 5.26%
Inorganica Chimica Acta	Inorganica Chimica Acta, 1, 5.26% Inorganica Chimica Acta 1 publication, 5.26%
Journal of Structural Chemistry	Journal of Structural Chemistry, 1, 5.26% Journal of Structural Chemistry 1 publication, 5.26%
CrystEngComm	CrystEngComm, 1, 5.26% CrystEngComm 1 publication, 5.26%
New Journal of Chemistry	New Journal of Chemistry, 1, 5.26% New Journal of Chemistry 1 publication, 5.26%
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Pleiades Publishing	Pleiades Publishing, 9, 47.37% Pleiades Publishing 9 publications, 47.37%
Elsevier	Elsevier, 4, 21.05% Elsevier 4 publications, 21.05%
Springer Nature	Springer Nature, 3, 15.79% Springer Nature 3 publications, 15.79%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 15.79% Royal Society of Chemistry (RSC) 3 publications, 15.79%
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Uvarova M. A. et al. Nickel(II) complexes with 2-Hfur and N-donors: The magnetic effects of the structural variations, thermal properties and antimycobacterial activity against Mycolicibacterium smegmatis // Polyhedron. 2021. Vol. 203. p. 115241.

GOST all authors (up to 50) Copy

Lutsenko I. A., Primakov P. V., Eremenko I. L., Bekker O. B., Petrova M. M., Zueva E. M., Khoroshilov A. V., Goloveshkin A. S., Efimov N. N., Babeshkin K. A., Nelyubina Y. V., Kiskin M. A., Uvarova M. A., Shmelev M. A., Lutsenko I. A., Kiskin M. A., Nelyubina Y. V., Babeshkin K. A., Efimov N. N., Goloveshkin A. S., Shmelev M. A., Khoroshilov A. V., Zueva E. M., Bekker O. B., Eremenko I. L. Nickel(II) complexes with 2-Hfur and N-donors: The magnetic effects of the structural variations, thermal properties and antimycobacterial activity against Mycolicibacterium smegmatis // Polyhedron. 2021. Vol. 203. p. 115241.

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RIS Copy

TY - JOUR

DO - 10.1016/j.poly.2021.115241

UR - https://doi.org/10.1016%2Fj.poly.2021.115241

TI - Nickel(II) complexes with 2-Hfur and N-donors: The magnetic effects of the structural variations, thermal properties and antimycobacterial activity against Mycolicibacterium smegmatis

T2 - Polyhedron

AU - Uvarova, Marina A

AU - Lutsenko, Irina A

AU - Kiskin, Mikhail A

AU - Nelyubina, Yulia V.

AU - Babeshkin, Konstantin A

AU - Efimov, Nikolay N.

AU - Goloveshkin, Alexander S.

AU - Shmelev, Maxim A

AU - Khoroshilov, Andrey V

AU - Zueva, Ekaterina M

AU - Petrova, Maria M

AU - Bekker, Olga B

AU - Eremenko, Igor L.

AU - Primakov, Petr V

AU - Lutsenko, Irina A

AU - Kiskin, Mikhail A.

AU - Nelyubina, Yulia V.

AU - Babeshkin, Konstantin A

AU - Efimov, Nikolay N.

AU - Goloveshkin, Alexander S.

AU - Shmelev, M. A.

AU - Khoroshilov, A. V.

AU - Zueva, Ekaterina M

AU - Bekker, Olga B

AU - Eremenko, Igor L.

PY - 2021

DA - 2021/07/01 00:00:00

PB - Elsevier

SP - 115241

VL - 203

SN - 0277-5387

ER -

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@article{2021_Uvarova,

author = {Marina A Uvarova and Irina A Lutsenko and Mikhail A Kiskin and Yulia V. Nelyubina and Konstantin A Babeshkin and Nikolay N. Efimov and Alexander S. Goloveshkin and Maxim A Shmelev and Andrey V Khoroshilov and Ekaterina M Zueva and Maria M Petrova and Olga B Bekker and Igor L. Eremenko and Petr V Primakov and Irina A Lutsenko and Mikhail A. Kiskin and Yulia V. Nelyubina and Konstantin A Babeshkin and Nikolay N. Efimov and Alexander S. Goloveshkin and M. A. Shmelev and A. V. Khoroshilov and Ekaterina M Zueva and Olga B Bekker and Igor L. Eremenko},

title = {Nickel(II) complexes with 2-Hfur and N-donors: The magnetic effects of the structural variations, thermal properties and antimycobacterial activity against Mycolicibacterium smegmatis},

journal = {Polyhedron},

year = {2021},

volume = {203},

publisher = {Elsevier},

month = {jul},

url = {https://doi.org/10.1016%2Fj.poly.2021.115241},

pages = {115241},

doi = {10.1016/j.poly.2021.115241}

}

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Polyhedron

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