Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.
Aleksei A Titov
1
,
Oleg A. Filippov
1
,
A F Smolyakov
1, 2, 3
,
Ivan A Godovikov
1
,
I A Godovikov
1
,
J R Shakirova
4
,
Sergey P. Tunik
4
,
I S Podkorytov
5
,
3
Publication type: Journal Article
Publication date: 2019-06-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
31247857
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The first example of trinuclear copper(I) and silver(I) pyrazolates adducts with a tertiary diphosphine (Ph2PCH2PPh2) retaining trimeric [MPz]3 core is reported. Despite rather strong M-P bonding, the complexes are able to undergo the dissociation of one M-P bond leading to the "merry-go-round" movement of P atoms over the M3 triangle. The copper complex displays emission from 1MLCT and 3MLCT states. The triplet and singlet states are separated by a relatively small energy gap (1080 cm-1) that triggers the thermally activated delayed fluorescence (TADF) behavior and leads to the worthy quantum yield of 41% at 298 K. The silver complex in the solid state and frozen solution shows dual emission originating from the 1IL and 3MLCT states that is dictated by the much higher energy difference between the emissive singlet and triplet as well as by the essentially different nature of these states.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
|
|
|
Inorganic Chemistry
5 publications, 13.16%
|
|
|
Dalton Transactions
5 publications, 13.16%
|
|
|
CrystEngComm
3 publications, 7.89%
|
|
|
Journal of Organometallic Chemistry
2 publications, 5.26%
|
|
|
Chemistry - A European Journal
2 publications, 5.26%
|
|
|
Chemical Reviews
2 publications, 5.26%
|
|
|
Crystals
1 publication, 2.63%
|
|
|
Molecules
1 publication, 2.63%
|
|
|
Mendeleev Communications
1 publication, 2.63%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.63%
|
|
|
Journal of Catalysis
1 publication, 2.63%
|
|
|
Inorganics
1 publication, 2.63%
|
|
|
Dyes and Pigments
1 publication, 2.63%
|
|
|
Magnetic Resonance in Chemistry
1 publication, 2.63%
|
|
|
Advanced Optical Materials
1 publication, 2.63%
|
|
|
Journal of Physical Chemistry Letters
1 publication, 2.63%
|
|
|
Journal of the American Chemical Society
1 publication, 2.63%
|
|
|
Inorganic Chemistry Frontiers
1 publication, 2.63%
|
|
|
Journal of Materials Chemistry C
1 publication, 2.63%
|
|
|
Journal of Structural Chemistry
1 publication, 2.63%
|
|
|
Chemical Communications
1 publication, 2.63%
|
|
|
Inorganic Chemistry Communication
1 publication, 2.63%
|
|
|
Chemical Engineering Journal
1 publication, 2.63%
|
|
|
Nature Communications
1 publication, 2.63%
|
|
|
1
2
3
4
5
|
Publishers
|
2
4
6
8
10
12
|
|
|
Royal Society of Chemistry (RSC)
11 publications, 28.95%
|
|
|
American Chemical Society (ACS)
9 publications, 23.68%
|
|
|
Elsevier
7 publications, 18.42%
|
|
|
Wiley
5 publications, 13.16%
|
|
|
MDPI
3 publications, 7.89%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 2.63%
|
|
|
Pleiades Publishing
1 publication, 2.63%
|
|
|
Springer Nature
1 publication, 2.63%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
38
Total citations:
38
Citations from 2024:
12
(31%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Titov A. A. et al. Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane. // Inorganic Chemistry. 2019. Vol. 58. No. 13. pp. 8645-8656.
GOST all authors (up to 50)
Copy
Titov A. A., Filippov O. A., Smolyakov A. F., Godovikov I. A., Godovikov I. A., Shakirova J. R., Shakirova J. R., Tunik S. P., Podkorytov I. S., Shubina E. S. Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane. // Inorganic Chemistry. 2019. Vol. 58. No. 13. pp. 8645-8656.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.inorgchem.9b00991
UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991
TI - Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.
T2 - Inorganic Chemistry
AU - Titov, Aleksei A
AU - Filippov, Oleg A.
AU - Smolyakov, A F
AU - Godovikov, Ivan A
AU - Godovikov, I A
AU - Shakirova, Julia R
AU - Shakirova, J R
AU - Tunik, Sergey P.
AU - Podkorytov, I S
AU - Shubina, Elena S.
PY - 2019
DA - 2019/06/19
PB - American Chemical Society (ACS)
SP - 8645-8656
IS - 13
VL - 58
PMID - 31247857
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Titov,
author = {Aleksei A Titov and Oleg A. Filippov and A F Smolyakov and Ivan A Godovikov and I A Godovikov and Julia R Shakirova and J R Shakirova and Sergey P. Tunik and I S Podkorytov and Elena S. Shubina},
title = {Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.},
journal = {Inorganic Chemistry},
year = {2019},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991},
number = {13},
pages = {8645--8656},
doi = {10.1021/acs.inorgchem.9b00991}
}
Cite this
MLA
Copy
Titov, Aleksei A., et al. “Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane..” Inorganic Chemistry, vol. 58, no. 13, Jun. 2019, pp. 8645-8656. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991.