Inorganic Chemistry

, том 58 , издание 13 , страницы 8645-8656

Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.

Тип публикации: Journal Article

Дата публикации: 2019-06-19

American Chemical Society (ACS)

Inorganic Chemistry

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SJR: 0.879

CiteScore: 7.5

Impact factor: 4.6

ISSN: 00201669, 1520510X

DOI: 10.1021/acs.inorgchem.9b00991

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PubMed ID: 31247857

Inorganic Chemistry

Physical and Theoretical Chemistry

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The first example of trinuclear copper(I) and silver(I) pyrazolates adducts with a tertiary diphosphine (Ph2PCH2PPh2) retaining trimeric [MPz]3 core is reported. Despite rather strong M-P bonding, the complexes are able to undergo the dissociation of one M-P bond leading to the "merry-go-round" movement of P atoms over the M3 triangle. The copper complex displays emission from 1MLCT and 3MLCT states. The triplet and singlet states are separated by a relatively small energy gap (1080 cm-1) that triggers the thermally activated delayed fluorescence (TADF) behavior and leads to the worthy quantum yield of 41% at 298 K. The silver complex in the solid state and frozen solution shows dual emission originating from the 1IL and 3MLCT states that is dictated by the much higher energy difference between the emissive singlet and triplet as well as by the essentially different nature of these states.

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Titov A. A. et al. Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane. // Inorganic Chemistry. 2019. Vol. 58. No. 13. pp. 8645-8656.

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Titov A. A., Filippov O. A., Smolyakov A. F., Godovikov I. A., Godovikov I. A., Shakirova J. R., Shakirova J. R., Tunik S. P., Podkorytov I. S., Shubina E. S. Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane. // Inorganic Chemistry. 2019. Vol. 58. No. 13. pp. 8645-8656.

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TY - JOUR

DO - 10.1021/acs.inorgchem.9b00991

UR - https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991

TI - Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.

T2 - Inorganic Chemistry

AU - Titov, Aleksei A

AU - Filippov, Oleg A.

AU - Smolyakov, A F

AU - Godovikov, Ivan A

AU - Godovikov, I A

AU - Shakirova, Julia R

AU - Shakirova, J R

AU - Tunik, Sergey P.

AU - Podkorytov, I S

AU - Shubina, Elena S.

PY - 2019

DA - 2019/06/19

PB - American Chemical Society (ACS)

SP - 8645-8656

IS - 13

VL - 58

PMID - 31247857

SN - 0020-1669

SN - 1520-510X

ER -

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@article{2019_Titov,

author = {Aleksei A Titov and Oleg A. Filippov and A F Smolyakov and Ivan A Godovikov and I A Godovikov and Julia R Shakirova and J R Shakirova and Sergey P. Tunik and I S Podkorytov and Elena S. Shubina},

title = {Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane.},

journal = {Inorganic Chemistry},

year = {2019},

volume = {58},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991},

number = {13},

pages = {8645--8656},

doi = {10.1021/acs.inorgchem.9b00991}

}

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Titov, Aleksei A., et al. “Luminescent Complexes of the Trinuclear Silver(I) and Copper(I) Pyrazolates Supported with Bis(diphenylphosphino)methane..” Inorganic Chemistry, vol. 58, no. 13, Jun. 2019, pp. 8645-8656. https://pubs.acs.org/doi/10.1021/acs.inorgchem.9b00991.

Издатель

American Chemical Society (ACS)

Журнал

Inorganic Chemistry

SCImago Q1

WOS Q1

БС1