Cyclobutadiene Arene Complexes of Rhodium and Iridium
Publication type: Journal Article
Publication date: 2016-08-23
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Reactions of [(C2H4)2RhCl]2 or [(coe)2RhCl]2 (coe = cyclooctene) with AgPF6 and arenes, followed by addition of 3-hexyne, give the cyclobutadiene complexes [(C4Et4)Rh(arene)]+ in 40–65% yield (arene = tert-butylbenzene, p-xylene, mesitylene, 4-mesitylbutanoic acid). In the absence of arenes, the hexaethylbenzene complex [(C4Et4)Rh(C6Et6)]+ is formed in 70% yield as a result of cyclotrimerization of 3-hexyne in the coordination sphere of rhodium. Similar reaction of [(coe)2IrCl]2 with AgPF6 and 3-hexyne leads to [(C4Et4)Ir(C6Et6)]+, which is apparently the first reported cyclobutadiene iridium complex. DFT calculations suggest that formation of the model cyclobutadiene complex [(C4Me4)Rh(C6H6)]+ from bis(alkyne) intermediate [(C2Me2)2Rh(C6H6)]+ can proceed via a metallacycle transition state with a low energy barrier of 14.5 kcal mol–1.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Mendeleev Communications
7 publications, 25%
|
|
|
Coordination Chemistry Reviews
3 publications, 10.71%
|
|
|
Organometallics
2 publications, 7.14%
|
|
|
Dalton Transactions
2 publications, 7.14%
|
|
|
ChemCatChem
2 publications, 7.14%
|
|
|
Journal of Organometallic Chemistry
2 publications, 7.14%
|
|
|
Angewandte Chemie - International Edition
1 publication, 3.57%
|
|
|
Bulletin of the Chemical Society of Japan
1 publication, 3.57%
|
|
|
International Journal of Quantum Chemistry
1 publication, 3.57%
|
|
|
ChemPlusChem
1 publication, 3.57%
|
|
|
Angewandte Chemie
1 publication, 3.57%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 3.57%
|
|
|
ACS Catalysis
1 publication, 3.57%
|
|
|
Applied Organometallic Chemistry
1 publication, 3.57%
|
|
|
New Journal of Chemistry
1 publication, 3.57%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
2
4
6
8
10
12
|
|
|
Elsevier
12 publications, 42.86%
|
|
|
Wiley
9 publications, 32.14%
|
|
|
American Chemical Society (ACS)
3 publications, 10.71%
|
|
|
Royal Society of Chemistry (RSC)
3 publications, 10.71%
|
|
|
Oxford University Press
1 publication, 3.57%
|
|
|
2
4
6
8
10
12
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
28
Total citations:
28
Citations from 2024:
3
(10%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shvydkiy N. V. et al. Cyclobutadiene Arene Complexes of Rhodium and Iridium // Organometallics. 2016. Vol. 35. No. 17. pp. 3025-3031.
GOST all authors (up to 50)
Copy
Shvydkiy N. V., Trifonova E. A., Shved A. M., Nelyubina Y. V., Chusov D., Perekalin D. S., Kudinov A. R. Cyclobutadiene Arene Complexes of Rhodium and Iridium // Organometallics. 2016. Vol. 35. No. 17. pp. 3025-3031.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acs.organomet.6b00539
UR - https://doi.org/10.1021/acs.organomet.6b00539
TI - Cyclobutadiene Arene Complexes of Rhodium and Iridium
T2 - Organometallics
AU - Shvydkiy, Nikita V
AU - Trifonova, Evgeniya A
AU - Shved, Andrei M
AU - Nelyubina, Yulia V.
AU - Chusov, Denis
AU - Perekalin, Dmitry S
AU - Kudinov, Alexander R
PY - 2016
DA - 2016/08/23
PB - American Chemical Society (ACS)
SP - 3025-3031
IS - 17
VL - 35
SN - 0276-7333
SN - 1520-6041
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Shvydkiy,
author = {Nikita V Shvydkiy and Evgeniya A Trifonova and Andrei M Shved and Yulia V. Nelyubina and Denis Chusov and Dmitry S Perekalin and Alexander R Kudinov},
title = {Cyclobutadiene Arene Complexes of Rhodium and Iridium},
journal = {Organometallics},
year = {2016},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.organomet.6b00539},
number = {17},
pages = {3025--3031},
doi = {10.1021/acs.organomet.6b00539}
}
Cite this
MLA
Copy
Shvydkiy, Nikita V., et al. “Cyclobutadiene Arene Complexes of Rhodium and Iridium.” Organometallics, vol. 35, no. 17, Aug. 2016, pp. 3025-3031. https://doi.org/10.1021/acs.organomet.6b00539.