Cyclobutadiene Arene Complexes of Rhodium and Iridium
Тип публикации: Journal Article
Дата публикации: 2016-08-23
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
Reactions of [(C2H4)2RhCl]2 or [(coe)2RhCl]2 (coe = cyclooctene) with AgPF6 and arenes, followed by addition of 3-hexyne, give the cyclobutadiene complexes [(C4Et4)Rh(arene)]+ in 40–65% yield (arene = tert-butylbenzene, p-xylene, mesitylene, 4-mesitylbutanoic acid). In the absence of arenes, the hexaethylbenzene complex [(C4Et4)Rh(C6Et6)]+ is formed in 70% yield as a result of cyclotrimerization of 3-hexyne in the coordination sphere of rhodium. Similar reaction of [(coe)2IrCl]2 with AgPF6 and 3-hexyne leads to [(C4Et4)Ir(C6Et6)]+, which is apparently the first reported cyclobutadiene iridium complex. DFT calculations suggest that formation of the model cyclobutadiene complex [(C4Me4)Rh(C6H6)]+ from bis(alkyne) intermediate [(C2Me2)2Rh(C6H6)]+ can proceed via a metallacycle transition state with a low energy barrier of 14.5 kcal mol–1.
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Shvydkiy N. V. et al. Cyclobutadiene Arene Complexes of Rhodium and Iridium // Organometallics. 2016. Vol. 35. No. 17. pp. 3025-3031.
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Shvydkiy N. V., Trifonova E. A., Shved A. M., Nelyubina Y. V., Chusov D., Perekalin D. S., Kudinov A. R. Cyclobutadiene Arene Complexes of Rhodium and Iridium // Organometallics. 2016. Vol. 35. No. 17. pp. 3025-3031.
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TY - JOUR
DO - 10.1021/acs.organomet.6b00539
UR - https://doi.org/10.1021/acs.organomet.6b00539
TI - Cyclobutadiene Arene Complexes of Rhodium and Iridium
T2 - Organometallics
AU - Shvydkiy, Nikita V
AU - Trifonova, Evgeniya A
AU - Shved, Andrei M
AU - Nelyubina, Yulia V.
AU - Chusov, Denis
AU - Perekalin, Dmitry S
AU - Kudinov, Alexander R
PY - 2016
DA - 2016/08/23
PB - American Chemical Society (ACS)
SP - 3025-3031
IS - 17
VL - 35
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2016_Shvydkiy,
author = {Nikita V Shvydkiy and Evgeniya A Trifonova and Andrei M Shved and Yulia V. Nelyubina and Denis Chusov and Dmitry S Perekalin and Alexander R Kudinov},
title = {Cyclobutadiene Arene Complexes of Rhodium and Iridium},
journal = {Organometallics},
year = {2016},
volume = {35},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.organomet.6b00539},
number = {17},
pages = {3025--3031},
doi = {10.1021/acs.organomet.6b00539}
}
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MLA
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Shvydkiy, Nikita V., et al. “Cyclobutadiene Arene Complexes of Rhodium and Iridium.” Organometallics, vol. 35, no. 17, Aug. 2016, pp. 3025-3031. https://doi.org/10.1021/acs.organomet.6b00539.