Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination
Тип публикации: Journal Article
Дата публикации: 2019-08-07
scimago Q2
wos Q1
БС1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The η6-fluorene cyclopentadienyl complexes [(η5-C5R5)M(η6-fluorene)](SbF6)2 (1: M = Co, R = Me; 2a: M = Rh, R = H; 2b: M = Ir, R = H) were synthesized by the iodide abstraction from [(η5-C5R5)MI2]n with AgSbF6 in the presence of fluorene. The procedure is also suitable for the synthesis of the indenyl derivatives [(η5-indenyl)M(η6-fluorene)](SbF6)2 (3a: M = Rh; 3b: M = Ir) starting from [(η5-indenyl)MI2]n. The structures of [1](SbF6)2 and [2b](SbF6)2 were determined by X-ray diffraction. The rhodium complex [2a](SbF6)2 readily undergoes the replacement of the fluorene ligand by mesitylene, being more reactive than the benzene derivative [CpRh(η6-C6H6)](SbF6)2. According to experimental data and DFT calculations, the fluorene elimination proceeds via a cascade of η6 → η5 → η1 haptotropic rearrangements. The complex [2b](SbF6)2 (at 1 mol % loading) effectively catalyzes the reductive amination reaction between aldehydes (or ketones) and primary aromatic (or secondary aliphatic) amines in the presence of car...
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
1
2
3
4
5
|
|
|
Journal of Organometallic Chemistry
5 публикаций, 31.25%
|
|
|
Russian Chemical Bulletin
2 публикации, 12.5%
|
|
|
Molecular Catalysis
1 публикация, 6.25%
|
|
|
Chemistry - A European Journal
1 публикация, 6.25%
|
|
|
Nature Synthesis
1 публикация, 6.25%
|
|
|
Coordination Chemistry Reviews
1 публикация, 6.25%
|
|
|
ChemistrySelect
1 публикация, 6.25%
|
|
|
Advanced Synthesis and Catalysis
1 публикация, 6.25%
|
|
|
Angewandte Chemie
1 публикация, 6.25%
|
|
|
Angewandte Chemie - International Edition
1 публикация, 6.25%
|
|
|
Organic Chemistry Frontiers
1 публикация, 6.25%
|
|
|
1
2
3
4
5
|
Издатели
|
1
2
3
4
5
6
7
|
|
|
Elsevier
7 публикаций, 43.75%
|
|
|
Wiley
5 публикаций, 31.25%
|
|
|
Springer Nature
3 публикации, 18.75%
|
|
|
Royal Society of Chemistry (RSC)
1 публикация, 6.25%
|
|
|
1
2
3
4
5
6
7
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
16
Всего цитирований:
16
Цитирований c 2024:
2
(12%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Kharitonov V. B. et al. Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination // Organometallics. 2019. Vol. 38. No. 16. pp. 3151-3158.
ГОСТ со всеми авторами (до 50)
Скопировать
Kharitonov V. B., Podyacheva E., Nelyubina Y. V., Muratov D. V., Peregudov A. S., Denisov G. L., Chusov D., Loginov D. A. Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination // Organometallics. 2019. Vol. 38. No. 16. pp. 3151-3158.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/acs.organomet.9b00378
UR - https://doi.org/10.1021/acs.organomet.9b00378
TI - Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination
T2 - Organometallics
AU - Kharitonov, Vladimir B.
AU - Podyacheva, Evgeniya
AU - Nelyubina, Yulia V.
AU - Muratov, Dmitry V.
AU - Peregudov, A. S.
AU - Denisov, Gleb L
AU - Chusov, Denis
AU - Loginov, Dmitry A.
PY - 2019
DA - 2019/08/07
PB - American Chemical Society (ACS)
SP - 3151-3158
IS - 16
VL - 38
SN - 0276-7333
SN - 1520-6041
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2019_Kharitonov,
author = {Vladimir B. Kharitonov and Evgeniya Podyacheva and Yulia V. Nelyubina and Dmitry V. Muratov and A. S. Peregudov and Gleb L Denisov and Denis Chusov and Dmitry A. Loginov},
title = {Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination},
journal = {Organometallics},
year = {2019},
volume = {38},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acs.organomet.9b00378},
number = {16},
pages = {3151--3158},
doi = {10.1021/acs.organomet.9b00378}
}
Цитировать
MLA
Скопировать
Kharitonov, Vladimir B., et al. “Fluorene Complexes of Group 9 Metals: Fluorene Effect and Application for Reductive Amination.” Organometallics, vol. 38, no. 16, Aug. 2019, pp. 3151-3158. https://doi.org/10.1021/acs.organomet.9b00378.