γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes
Тип публикации: Journal Article
Дата публикации: 2017-09-01
scimago Q1
wos Q1
БС1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5
ISSN: 15237060, 15237052
PubMed ID:
28862865
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Краткое описание
γ-Amino butyric acid (GABA) is the chief inhibitory neurotransmitter in the mammalian central nervous system. Many GABA derivatives are used clinically to prevent or treat neurodegenerative diseases. Copper-catalyzed carboamination of alkenes offers an efficient method to fashion the core structure of GABA derivatives from alkenes. In this reaction, acetonitrile serves as the source of the carbon and nitrogen functionalities used to difunctionalize alkenes. Experimental and density functional theory (DFT) studies were carried out to investigate the mechanism of the reaction, and a copper-catalyzed radical-polar crossover mechanism is proposed.
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ГОСТ
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Zhu N. et al. γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes // Organic Letters. 2017. Vol. 19. No. 18. pp. 4718-4721.
ГОСТ со всеми авторами (до 50)
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Zhu N., Wang T., Ge L., Li Y., Zhang X., Bao H. γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes // Organic Letters. 2017. Vol. 19. No. 18. pp. 4718-4721.
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TY - JOUR
DO - 10.1021/acs.orglett.7b01969
UR - https://doi.org/10.1021/acs.orglett.7b01969
TI - γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes
T2 - Organic Letters
AU - Zhu, Nengbo
AU - Wang, Ting
AU - Ge, Liang
AU - Li, Yajun
AU - Zhang, Xinhao
AU - Bao, Hongli
PY - 2017
DA - 2017/09/01
PB - American Chemical Society (ACS)
SP - 4718-4721
IS - 18
VL - 19
PMID - 28862865
SN - 1523-7060
SN - 1523-7052
ER -
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BibTex (до 50 авторов)
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@article{2017_Zhu,
author = {Nengbo Zhu and Ting Wang and Liang Ge and Yajun Li and Xinhao Zhang and Hongli Bao},
title = {γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes},
journal = {Organic Letters},
year = {2017},
volume = {19},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/acs.orglett.7b01969},
number = {18},
pages = {4718--4721},
doi = {10.1021/acs.orglett.7b01969}
}
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MLA
Скопировать
Zhu, Nengbo, et al. “γ-Amino Butyric Acid (GABA) Synthesis Enabled by Copper-Catalyzed Carboamination of Alkenes.” Organic Letters, vol. 19, no. 18, Sep. 2017, pp. 4718-4721. https://doi.org/10.1021/acs.orglett.7b01969.