ACS Catalysis

, volume 3 , issue 9 , pages 1951-1955

Chiral Octahedral Complexes of Co^III As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions

Yu. N. Belokon' ¹

Viktor Maleev ¹

MICHAEL J. NORTH ²

Vladimir A Larionov ¹

Tatyana F Savelyeva ¹

Aike Nijland ³

Yuliya V. Nelyubina ¹

Hide authors affiliations Show authors affiliations: 3 affiliations

Nesmeyanov Institute of Organoelement Compounds, 119991, Moscow, Vavilov 28, Russia |

School of Chemistry, Newcastle University, Bedson Building, Newcastle upon Tyne, NE1 7RU, United Kingdom |

Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747AG, Groningen, The Netherlands |

Publication type: Journal Article

Publication date: 2013-07-31

American Chemical Society (ACS)

ACS Catalysis

scimago Q1

wos Q1

SJR: 3.782

CiteScore: 19.5

Impact factor: 13.1

ISSN: 21555435

DOI: 10.1021/cs400409d

Copy DOI

General Chemistry

Catalysis

Abstract

Stereochemically inert and positively charged chiral complexes of CoIII prepared from Schiff bases derived from chiral diamines and salicylaldehydes were shown to be efficient catalysts of the asymmetric phase transfer benchmark reaction of alkylation of O’Donnell’s substrate with alkyl halides. The enantiomeric purities of the reaction products were up to 92%.

Found

17 citations

Larionov Vladimir

🥼 🤝

DSc in Chemistry

54 publications, 1 090 citations, 111 reviews

h-index: 18

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Peoples' Friendship University of Russia

Research interests

Asymmetric catalysis

5 citations

Medvedev Michael

PhD in Physics and Mathematics, associate professor

85 publications, 2 093 citations, 7 reviews

h-index: 19

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

4 citations

Khromova Olga

🤝

PhD in Chemistry

5 publications, 50 citations

h-index: 4

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Asymmetric catalysis

Asymmetric metal complex catalysis

Asymmetric synthesis

Catalysis

Coordination Chemistry

Crystal Chemistry

Hydrogen-bonded organic polymers

Metal-organic frameworks

Organometallic Chemistry

1 citation

Eremenko Igor

DSc in Chemistry, professor, full member of the Russian Academy of Sciences

675 publications, 7 815 citations, 29 reviews

h-index: 35

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

1 citation

Nelyubina Yulia

🤝

DSc in Chemistry

507 publications, 7 656 citations, 1 review

h-index: 38

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Metal-organic frameworks

Quantum technologies

Sensors

1 citation

Prima Darya

🥼 🤝

PhD in Chemistry

21 publications, 413 citations

h-index: 9

N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences

Heterocyclic compounds

Organic Chemistry

Organic synthesis

Organometallic Chemistry

Perfluorinated compounds

1 citation

Pavlov Alexander

🥼 🤝

DSc in Chemistry

120 publications, 1 983 citations

h-index: 23

Bauman Moscow State Technical University

Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences

Mendeleev University of Chemical Technology of Russia

Research interests

Digital Chemistry

Digital Materials Science

Molecular magnetism

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Cite this

GOST |

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GOST Copy

Belokon' Y. N. et al. Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions // ACS Catalysis. 2013. Vol. 3. No. 9. pp. 1951-1955.

GOST all authors (up to 50) Copy

Belokon' Y. N., Maleev V., NORTH M. J., Larionov V. A., Savelyeva T. F., Nijland A., Nelyubina Y. V. Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions // ACS Catalysis. 2013. Vol. 3. No. 9. pp. 1951-1955.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/cs400409d

UR - https://doi.org/10.1021/cs400409d

TI - Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions

T2 - ACS Catalysis

AU - Belokon', Yu. N.

AU - Maleev, Viktor

AU - NORTH, MICHAEL J.

AU - Larionov, Vladimir A

AU - Savelyeva, Tatyana F

AU - Nijland, Aike

AU - Nelyubina, Yuliya V.

PY - 2013

DA - 2013/07/31

PB - American Chemical Society (ACS)

SP - 1951-1955

IS - 9

VL - 3

SN - 2155-5435

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2013_Belokon',

author = {Yu. N. Belokon' and Viktor Maleev and MICHAEL J. NORTH and Vladimir A Larionov and Tatyana F Savelyeva and Aike Nijland and Yuliya V. Nelyubina},

title = {Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions},

journal = {ACS Catalysis},

year = {2013},

volume = {3},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/cs400409d},

number = {9},

pages = {1951--1955},

doi = {10.1021/cs400409d}

}

MLA

Cite this

MLA Copy

Belokon', Yu. N., et al. “Chiral Octahedral Complexes of CoIII As a Family of Asymmetric Catalysts Operating under Phase Transfer Conditions.” ACS Catalysis, vol. 3, no. 9, Jul. 2013, pp. 1951-1955. https://doi.org/10.1021/cs400409d.

Publisher

American Chemical Society (ACS)

Journal

ACS Catalysis

scimago Q1

wos Q1

SJR

3.782

CiteScore

19.5

Impact factor

13.1

ISSN

21555435 (Print, Electronic)

Labs

Molecular Structure Research Center

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