Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes
Suriyakan Vongtragool
1
,
Boris Gorshunov
1
,
Martin Dressel
1
,
J. Krzystek
1
,
David M. Eichhorn
1
,
Publication type: Journal Article
Publication date: 2003-02-19
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
12639108
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Novel far-infrared (FIR) absorption spectroscopy in conjunction with multiple, fixed external magnetic fields (FIR magnetic spectroscopy, FIRMS) has been used to investigate pseudotetrahedral complexes with the formula M(PPh(3))(2)Cl(2) (M = Ni, Zn; Ph = C(6)H(5)). Crystal structures have been reported for the Ni complex; we report the structure of the Zn complex. Transmission spectra at 5 K of Ni(PPh(3))(2)Cl(2) (S = 1) at zero magnetic field exhibit absorption bands at 11.41, 15.28, and 23.0 cm(-1). The two lower frequency bands show great sensitivity to external magnetic field, and their field dependence is as expected for electron spin transitions allowing precise determination of the following parameters: |D| = 13.35(1) cm(-1), |E| = 1.93(1) cm(-1), g(x,y) = 2.20(1), g(z) = 2.00(1). Corresponding spectra of Zn(PPh(3))(2)Cl(2) (S = 0) exhibit bands only at >20 cm(-1), which show no field dependence. FIRMS is a promising technique for direct investigation of the electronic structure of high-spin transition metal complexes.
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GOST
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Vongtragool S. et al. Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes // Inorganic Chemistry. 2003. Vol. 42. No. 6. pp. 1788-1790.
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Vongtragool S., Gorshunov B., Dressel M., Krzystek J., Eichhorn D. M., Telser J. Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes // Inorganic Chemistry. 2003. Vol. 42. No. 6. pp. 1788-1790.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ic030013o
UR - https://doi.org/10.1021/ic030013o
TI - Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes
T2 - Inorganic Chemistry
AU - Vongtragool, Suriyakan
AU - Gorshunov, Boris
AU - Dressel, Martin
AU - Krzystek, J.
AU - Eichhorn, David M.
AU - Telser, Joshua
PY - 2003
DA - 2003/02/19
PB - American Chemical Society (ACS)
SP - 1788-1790
IS - 6
VL - 42
PMID - 12639108
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2003_Vongtragool,
author = {Suriyakan Vongtragool and Boris Gorshunov and Martin Dressel and J. Krzystek and David M. Eichhorn and Joshua Telser},
title = {Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes},
journal = {Inorganic Chemistry},
year = {2003},
volume = {42},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ic030013o},
number = {6},
pages = {1788--1790},
doi = {10.1021/ic030013o}
}
Cite this
MLA
Copy
Vongtragool, Suriyakan, et al. “Direct observation of fine structure transitions in a paramagnetic nickel(II) complex using far-infrared magnetic spectroscopy: A new method for studying high-spin transition metal complexes.” Inorganic Chemistry, vol. 42, no. 6, Feb. 2003, pp. 1788-1790. https://doi.org/10.1021/ic030013o.
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