Langmuir

, том 14 , издание 2 , страницы 252-259

Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation

A. T. Dembo ¹

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Institute of Crystallography, Russian Academy of Sciences, 59 Leninsky Pr., 117333 Moscow, Russia |

Тип публикации: Journal Article

Дата публикации: 1998-01-01

American Chemical Society (ACS)

Langmuir

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wos Q2

БС1

SJR: 0.763

CiteScore: 6.0

Impact factor: 3.9

ISSN: 07437463, 15205827

DOI: 10.1021/la970527y

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Spectroscopy

Electrochemistry

Condensed Matter Physics

General Materials Science

Surfaces and Interfaces

Краткое описание

The interaction of polyelectrolyte gel/oppositely charged surfactant complexes with AgNO3 and H2PtCl6 was investigated. Three kinds of gel/surfactant complexes were studied: a complex of the anionic gel of poly(methacrylic acid) with the cationic surfactant cetylpyridinium chloride and complexes of the cationic gel of poly(diallyldimethylammonium chloride) with two anionic surfactants: sodium dodecyl sulfate and sodium dodecylbenzenesulfonate. After reduction of metal compounds by hydrazine−hydrate, sodium borohydride, or UV-irradiation, Pt and Ag metal particles embedded in the body of the hydrogel were formed. The degree of metal ion exchange was higher for the oppositely charged metal ion and the polyelectrolyte gel; i.e., Ag+ is strongly absorbed by the complex poly(methacrylic acid)/cationic surfactant, while PtCl62- ions are mainly consumed by the complex of poly(diallyldimethylammonium chloride) gel with anionic surfactants. Small-angle X-ray scattering data indicated different structural changes...

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Хохлов Алексей

д.ф.-м.н., проф., академик, Российская академия наук

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Московский государственный университет имени М.В. Ломоносова

Институт элементоорганических соединений им. А.Н. Несмеянова РАН

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Bronstein L. et al. Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation // Langmuir. 1998. Vol. 14. No. 2. pp. 252-259.

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Dembo A. T. Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation // Langmuir. 1998. Vol. 14. No. 2. pp. 252-259.

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TY - JOUR

DO - 10.1021/la970527y

UR - https://doi.org/10.1021/la970527y

TI - Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation

T2 - Langmuir

AU - Dembo, A. T.

PY - 1998

DA - 1998/01/01

PB - American Chemical Society (ACS)

SP - 252-259

IS - 2

VL - 14

SN - 0743-7463

SN - 1520-5827

ER -

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@article{1998_Bronstein,

author = {A. T. Dembo},

title = {Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation},

journal = {Langmuir},

year = {1998},

volume = {14},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/la970527y},

number = {2},

pages = {252--259},

doi = {10.1021/la970527y}

}

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Bronstein, L.M., et al. “Complexes of polyelectrolyte gels with oppositely charged surfactants: Interaction with metal ions and metal nanoparticle formation.” Langmuir, vol. 14, no. 2, Jan. 1998, pp. 252-259. https://doi.org/10.1021/la970527y.