Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent
Publication type: Journal Article
Publication date: 2014-09-16
scimago Q1
wos Q1
SJR: 1.235
CiteScore: 8.7
Impact factor: 5.0
ISSN: 15237060, 15237052
PubMed ID:
25225971
Organic Chemistry
Biochemistry
Physical and Theoretical Chemistry
Abstract
A highly efficient one-step Rh-catalyzed preparation of reduced Knoevenagel adducts of various aldehydes and ketones with active methylene compounds has been developed. The protocol does not require an external hydrogen source and employs carbon monoxide as a deoxygenative agent. The use of malonic acid or cyanoacetamide enabled efficient formal deoxygenative addition of methyl acetate or acetonitrile to aldehydes. The developed methodology was applied to the synthesis of the precursors of biomedically important compounds.
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28
Total citations:
28
Citations from 2025:
2
(7.14%)
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GOST
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Kolesnikov P. N. et al. Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent // Organic Letters. 2014. Vol. 16. No. 19. pp. 5068-5071.
GOST all authors (up to 50)
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Kolesnikov P. N., Usanov D. A., Barablina E. A., Maleev V., Chusov D. Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent // Organic Letters. 2014. Vol. 16. No. 19. pp. 5068-5071.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ol502424t
UR - https://doi.org/10.1021/ol502424t
TI - Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent
T2 - Organic Letters
AU - Kolesnikov, Pavel N
AU - Usanov, Dmitry A.
AU - Barablina, Evgeniya A
AU - Maleev, Viktor
AU - Chusov, Denis
PY - 2014
DA - 2014/09/16
PB - American Chemical Society (ACS)
SP - 5068-5071
IS - 19
VL - 16
PMID - 25225971
SN - 1523-7060
SN - 1523-7052
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Kolesnikov,
author = {Pavel N Kolesnikov and Dmitry A. Usanov and Evgeniya A Barablina and Viktor Maleev and Denis Chusov},
title = {Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent},
journal = {Organic Letters},
year = {2014},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ol502424t},
number = {19},
pages = {5068--5071},
doi = {10.1021/ol502424t}
}
Cite this
MLA
Copy
Kolesnikov, Pavel N., et al. “Atom- and Step-Economical Preparation of Reduced Knoevenagel Adducts Using CO as a Deoxygenative Agent.” Organic Letters, vol. 16, no. 19, Sep. 2014, pp. 5068-5071. https://doi.org/10.1021/ol502424t.
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