Springer Nature
Russian Chemical Bulletin
,  volume 53 ,  issue 3 ,  pages 641-646

1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine

Publication type: Journal Article
Publication date: 2004-03-01
Springer Nature
scimago Q3
SJR: 0.305
CiteScore: 2.8
Impact factor: —
ISSN: 10665285, 15739171
General Chemistry
Abstract
Using the synthesis of 1,2-bis(methylamino)ethane-1,2-diol dihydrochloride (5) as an example, it was demonstrated that aliphatic α-aminocarbinols can be stabilized as hydrochlorides. The reaction of compound 5 with N-chloromethylamine in CHCl3 in the presence of K2CO3 afforded 1,2,1",2"-tetramethyl-3,3"-bidiaziridine as a mixture of diastereomers (a racemate and a meso form). The meso form was isolated in the individual state and its structure was established by X-ray diffraction analysis. The kinetics of inversional epimerization was studied.
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Petukhova V. Yu. et al. 1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine // Russian Chemical Bulletin. 2004. Vol. 53. No. 3. pp. 641-646.
GOST all authors (up to 50) Copy
Petukhova V. Yu., Makhova N. N., Ananikov V. P., Strelenko Y., Fedyanin I. V. 1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine // Russian Chemical Bulletin. 2004. Vol. 53. No. 3. pp. 641-646.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1023/B:RUCB.0000035650.08227.36
UR - https://doi.org/10.1023/B:RUCB.0000035650.08227.36
TI - 1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine
T2 - Russian Chemical Bulletin
AU - Petukhova, V Yu
AU - Makhova, N N
AU - Ananikov, V P
AU - Strelenko, Yu.A.
AU - Fedyanin, I V
PY - 2004
DA - 2004/03/01
PB - Springer Nature
SP - 641-646
IS - 3
VL - 53
SN - 1066-5285
SN - 1573-9171
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2004_Petukhova,
author = {V Yu Petukhova and N N Makhova and V P Ananikov and Yu.A. Strelenko and I V Fedyanin},
title = {1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine},
journal = {Russian Chemical Bulletin},
year = {2004},
volume = {53},
publisher = {Springer Nature},
month = {mar},
url = {https://doi.org/10.1023/B:RUCB.0000035650.08227.36},
number = {3},
pages = {641--646},
doi = {10.1023/B:RUCB.0000035650.08227.36}
}
MLA
Cite this
MLA Copy
Petukhova, V. Yu., et al. “1,2-Bis(methylamino)ethane-1,2-diol dihydrochloride as a new precursor of 1,2,1′,2′-tetramethyl-3,3′-bidiaziridine.” Russian Chemical Bulletin, vol. 53, no. 3, Mar. 2004, pp. 641-646. https://doi.org/10.1023/B:RUCB.0000035650.08227.36.