Chemical Communications, volume 58, issue 6, pages 859-862
Amine-boranes reactions promoted by lanthanide(ii ) ions
Alexander A Kissel
1
,
Alexander N Selikhov
1, 2
,
Oleg A. Filippov
1
,
Alexander A. Trifonov
1, 2
,
Publication type: Journal Article
Publication date: 2022-01-01
Journal:
Chemical Communications
scimago Q1
wos Q2
SJR: 1.133
CiteScore: 8.6
Impact factor: 4.3
ISSN: 13597345, 1364548X
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films
General Chemistry
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Catalysis
Abstract
The catalytic activity in amine-borane dehydrogenation is shown for the first time for Ln(II) species using complexes [{(p-tBu-C6H4)2CH}2M·L] (M = Yb, Sm, L = (DME)2, TMEDA). The protonation of M(II)-C bonds with HNR1R2BH3 affords amidoborane complexes [M(NR1R2BH3)2L], which under excess HNMe2BH3 transform to [NMe2BH2NMe2BH3]- derivatives, both serving as the dehydrocoupling intermediates.
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Kirkina V. A. et al. Amine-boranes reactions promoted by lanthanide(ii) ions // Chemical Communications. 2022. Vol. 58. No. 6. pp. 859-862.
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Kirkina V. A., Kissel A. A., Selikhov A. N., Nelyubina Y. V., Filippov O. A., Belkova N. V., Trifonov A. A., Shubina E. S. Amine-boranes reactions promoted by lanthanide(ii) ions // Chemical Communications. 2022. Vol. 58. No. 6. pp. 859-862.
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TY - JOUR
DO - 10.1039/d1cc06401k
UR - https://xlink.rsc.org/?DOI=D1CC06401K
TI - Amine-boranes reactions promoted by lanthanide(ii) ions
T2 - Chemical Communications
AU - Kirkina, Vladislava A
AU - Kissel, Alexander A
AU - Selikhov, Alexander N
AU - Nelyubina, Yulia V.
AU - Filippov, Oleg A.
AU - Belkova, Natalia V
AU - Trifonov, Alexander A.
AU - Shubina, Elena S.
PY - 2022
DA - 2022/01/01
PB - Royal Society of Chemistry (RSC)
SP - 859-862
IS - 6
VL - 58
SN - 1359-7345
SN - 1364-548X
ER -
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BibTex (up to 50 authors)
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@article{2022_Kirkina,
author = {Vladislava A Kirkina and Alexander A Kissel and Alexander N Selikhov and Yulia V. Nelyubina and Oleg A. Filippov and Natalia V Belkova and Alexander A. Trifonov and Elena S. Shubina},
title = {Amine-boranes reactions promoted by lanthanide(ii) ions},
journal = {Chemical Communications},
year = {2022},
volume = {58},
publisher = {Royal Society of Chemistry (RSC)},
month = {jan},
url = {https://xlink.rsc.org/?DOI=D1CC06401K},
number = {6},
pages = {859--862},
doi = {10.1039/d1cc06401k}
}
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Kirkina, Vladislava A., et al. “Amine-boranes reactions promoted by lanthanide(ii) ions.” Chemical Communications, vol. 58, no. 6, Jan. 2022, pp. 859-862. https://xlink.rsc.org/?DOI=D1CC06401K.