Royal Society of Chemistry (RSC)
Green Chemistry
,  volume 20 ,  issue 7 ,  pages 1467-1471

Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols

Ashot V Arzumanyan 1
, 
Irina K Goncharova 1
, 
Roman G. Novikov 2
, 
Sergey A Milenin 3
, 
Konstantin L Boldyrev 3
, 
Pavel N. Solyev 2
, 
Yaroslav V. Tkachev 2
, 
Alexander D Volodin 1
, 
Alexander F. Smol’yakov 1, 4
, 
Alexander Korlyukov 1, 5
, 
Aziz M. Muzafarov 1, 3
1
 
2
 
3
 
4
 
5
 
Publication type: Journal Article
Publication date: 2018-02-28
Royal Society of Chemistry (RSC)
scimago Q1
wos Q1
SJR: 1.928
CiteScore: 16.1
Impact factor: 9.2
ISSN: 14639262, 14639270
Environmental Chemistry
Pollution
Abstract
A highly efficient preparative method for the synthesis of siloxanols based on aerobic Co(OAc)2 or Cu(OAc)2/NHPI-catalyzed oxidation of hydride siloxanes using “green”, commercially available, simple inexpensive reagents and mild reaction conditions has been proposed. This is a general reaction for the synthesis of mono-, oligo- and polymeric siloxanols with various structures (linear, branched and cyclic).
Found 
Found 
7 citations
Anisimov Anton
🥼 🤝
PhD in Chemistry
69 publications,  1 028 citations,  5 reviews
h-index: 19
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Moscow Institute of Physics and Technology
Moscow Institute of Physics and Technology
Tula State Pedagogical University named after L.N. Tolstoy
Tula State Pedagogical University named after L.N. Tolstoy
Research interests
"Smart" materials
Green chemistry
High molecular weight compounds
Organosilicon Chemistry
6 citations
Goncharova Irina
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PhD in Chemistry
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h-index: 8
A.V. Topchiev Institute of Petrochemical Synthesis RAS
A.V. Topchiev Institute of Petrochemical Synthesis RAS
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Catalysis
Chemistry of organoelement compounds
Organic synthesis
Organometallic Chemistry
Polymer Chemistry
Selective liquid phase oxidation
4 citations
Milenin Sergey
🥼 🤝
PhD in Chemistry
57 publications,  668 citations,  14 reviews
h-index: 14
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Research interests
3D printing
Dendrimers
Green chemistry
Polymer science
Silicone materials
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Kholodkov Dmitry
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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Krylov Igor
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78 publications,  1 876 citations,  18 reviews
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N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
Research interests
Green chemistry
Organic Chemistry
Organic electrochemistry
Organic synthesis
Photochemistry
Plant protection
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Drozdov Fedor
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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences
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"Smart" materials
3D printing
Nature-like technologies
Organic synthesis
Organometallic Chemistry
Polymer science
2 citations
Ardabevskaia Sofia
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Tula State Pedagogical University named after L.N. Tolstoy
Tula State Pedagogical University named after L.N. Tolstoy
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Research interests
Dendrimers
Organosilicon Chemistry
Polymer science
2 citations
Temnikov Maxim
PhD in Chemistry
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Tula State Pedagogical University named after L.N. Tolstoy
Tula State Pedagogical University named after L.N. Tolstoy
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Chemistry of organic and organoelement compounds; chemistry of polymers; production of materials
Green chemistry
High molecular weight compounds
2 citations
Krizhanovskiy Ilya
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h-index: 5
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Tula State Pedagogical University named after L.N. Tolstoy
Tula State Pedagogical University named after L.N. Tolstoy
Research interests
High molecular weight compounds
Organosilicon Chemistry
Organosilicon compounds
1 citation
Dorovatovskii Pavel
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National Research Centre "Kurchatov Institute"
National Research Centre "Kurchatov Institute"
1 citation
Shevchenko Vitaliy
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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
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A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
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Segida Oleg
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h-index: 8
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences
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Bezlepkina Kseniya
PhD in Chemistry
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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Tula State Pedagogical University named after L.N. Tolstoy
Tula State Pedagogical University named after L.N. Tolstoy
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🥼 🤝
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Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
Enikolopov Institute of Synthetic Polymeric Materials of the Russian Academy of Sciences
1 citation
Minyaylo Ekaterina
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h-index: 4
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences
Research interests
Dendrimers
Organosilicon Compounds
Polyhedral carboranes
Polymer science
1 citation
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DSc in Chemistry, professor, associate member of the Russian Academy of Sciences 
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National Research Centre "Kurchatov Institute"
National Research Centre "Kurchatov Institute"
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Arzumanyan A. V. et al. Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols // Green Chemistry. 2018. Vol. 20. No. 7. pp. 1467-1471.
GOST all authors (up to 50) Copy
Arzumanyan A. V., Goncharova I. K., Novikov R. G., Milenin S. A., Boldyrev K. L., Solyev P. N., Tkachev Y. V., Volodin A. D., Smol’yakov A. F., Korlyukov A., Muzafarov A. M. Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols // Green Chemistry. 2018. Vol. 20. No. 7. pp. 1467-1471.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1039/C8GC00424B
UR - https://doi.org/10.1039/C8GC00424B
TI - Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols
T2 - Green Chemistry
AU - Arzumanyan, Ashot V
AU - Goncharova, Irina K
AU - Novikov, Roman G.
AU - Milenin, Sergey A
AU - Boldyrev, Konstantin L
AU - Solyev, Pavel N.
AU - Tkachev, Yaroslav V.
AU - Volodin, Alexander D
AU - Smol’yakov, Alexander F.
AU - Korlyukov, Alexander
AU - Muzafarov, Aziz M.
PY - 2018
DA - 2018/02/28
PB - Royal Society of Chemistry (RSC)
SP - 1467-1471
IS - 7
VL - 20
SN - 1463-9262
SN - 1463-9270
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Arzumanyan,
author = {Ashot V Arzumanyan and Irina K Goncharova and Roman G. Novikov and Sergey A Milenin and Konstantin L Boldyrev and Pavel N. Solyev and Yaroslav V. Tkachev and Alexander D Volodin and Alexander F. Smol’yakov and Alexander Korlyukov and Aziz M. Muzafarov},
title = {Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols},
journal = {Green Chemistry},
year = {2018},
volume = {20},
publisher = {Royal Society of Chemistry (RSC)},
month = {feb},
url = {https://doi.org/10.1039/C8GC00424B},
number = {7},
pages = {1467--1471},
doi = {10.1039/C8GC00424B}
}
MLA
Cite this
MLA Copy
Arzumanyan, Ashot V., et al. “Aerobic Co or Cu/NHPI-catalyzed oxidation of hydride siloxanes: synthesis of siloxanols.” Green Chemistry, vol. 20, no. 7, Feb. 2018, pp. 1467-1471. https://doi.org/10.1039/C8GC00424B.