Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power
Klim O Biriukov
1, 2, 3, 4
,
Mikhail M Vinogradov
1, 2, 3, 4
,
Oleg I Afanasyev
1, 2, 3, 4
,
Dmitry V. Vasilyev
5, 6, 7, 8, 9
,
Alexey A. Tsygankov
1, 2, 3, 4
,
Maria Godovikova
1, 2, 3, 4
,
Dmitry A. Loginov
1, 10
,
Denis Chusov
1, 2, 3, 4, 10, 11, 12
2
3
Moscow
4
RUSSIAN FEDERATION
|
5
8
91058 Erlangen
|
9
GERMANY
|
12
Moscow 117997
Publication type: Journal Article
Publication date: 2021-05-26
scimago Q2
wos Q2
SJR: 1.026
CiteScore: 8.0
Impact factor: 4.2
ISSN: 20444753, 20444761
Catalysis
Abstract
Herein, we present the first example of Os-catalyzed efficient reductive amination under water–gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.
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11
Total citations:
11
Citations from 2025:
1
(9.09%)
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GOST
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Biriukov K. O. et al. Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power // Catalysis Science and Technology. 2021. Vol. 11. No. 14. pp. 4922-4930.
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Biriukov K. O., Vinogradov M. M., Afanasyev O. I., Vasilyev D. V., Tsygankov A. A., Godovikova M., Nelyubina Y. V., Loginov D. A., Chusov D. Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power // Catalysis Science and Technology. 2021. Vol. 11. No. 14. pp. 4922-4930.
Cite this
RIS
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TY - JOUR
DO - 10.1039/D1CY00695A
UR - https://xlink.rsc.org/?DOI=D1CY00695A
TI - Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power
T2 - Catalysis Science and Technology
AU - Biriukov, Klim O
AU - Vinogradov, Mikhail M
AU - Afanasyev, Oleg I
AU - Vasilyev, Dmitry V.
AU - Tsygankov, Alexey A.
AU - Godovikova, Maria
AU - Nelyubina, Yulia V.
AU - Loginov, Dmitry A.
AU - Chusov, Denis
PY - 2021
DA - 2021/05/26
PB - Royal Society of Chemistry (RSC)
SP - 4922-4930
IS - 14
VL - 11
SN - 2044-4753
SN - 2044-4761
ER -
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BibTex (up to 50 authors)
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@article{2021_Biriukov,
author = {Klim O Biriukov and Mikhail M Vinogradov and Oleg I Afanasyev and Dmitry V. Vasilyev and Alexey A. Tsygankov and Maria Godovikova and Yulia V. Nelyubina and Dmitry A. Loginov and Denis Chusov},
title = {Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power},
journal = {Catalysis Science and Technology},
year = {2021},
volume = {11},
publisher = {Royal Society of Chemistry (RSC)},
month = {may},
url = {https://xlink.rsc.org/?DOI=D1CY00695A},
number = {14},
pages = {4922--4930},
doi = {10.1039/D1CY00695A}
}
Cite this
MLA
Copy
Biriukov, Klim O., et al. “Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power.” Catalysis Science and Technology, vol. 11, no. 14, May. 2021, pp. 4922-4930. https://xlink.rsc.org/?DOI=D1CY00695A.