Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor
Publication type: Journal Article
Publication date: 2021-10-13
scimago Q2
wos Q2
SJR: 0.559
CiteScore: 4.6
Impact factor: 2.3
ISSN: 00397881, 1437210X
Catalysis
Organic Chemistry
Abstract
A ruthenium complex with a chiral arene ligand [(camphor–arene)RuCl2]2 was synthesized by the reaction of RuCl3·nH2O with a chiral diene which was obtained from natural camphor in three steps. This complex catalyzed the asymmetric hydrogenation of acetophenone (64–85% ee), but decomposed in catalytic reactions involving C–H activation of 2-phenylpyridine or benzoic acid derivatives.
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Perekalin D. S. et al. Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor // Synthesis. 2021. Vol. 54. No. 21. pp. 4721-4726.
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Perekalin D. S., Pototskiy R. A., Boym M. A., Nelyubina Y. V. Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor // Synthesis. 2021. Vol. 54. No. 21. pp. 4721-4726.
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RIS
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TY - JOUR
DO - 10.1055/a-1668-2075
UR - https://doi.org/10.1055/a-1668-2075
TI - Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor
T2 - Synthesis
AU - Perekalin, Dmitry S
AU - Pototskiy, Roman A
AU - Boym, Mikhail A
AU - Nelyubina, Yulia V.
PY - 2021
DA - 2021/10/13
PB - Georg Thieme Verlag KG
SP - 4721-4726
IS - 21
VL - 54
SN - 0039-7881
SN - 1437-210X
ER -
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BibTex (up to 50 authors)
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@article{2021_Perekalin,
author = {Dmitry S Perekalin and Roman A Pototskiy and Mikhail A Boym and Yulia V. Nelyubina},
title = {Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor},
journal = {Synthesis},
year = {2021},
volume = {54},
publisher = {Georg Thieme Verlag KG},
month = {oct},
url = {https://doi.org/10.1055/a-1668-2075},
number = {21},
pages = {4721--4726},
doi = {10.1055/a-1668-2075}
}
Cite this
MLA
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Perekalin, Dmitry S., et al. “Synthesis of Ruthenium Catalysts with a Chiral Arene Ligand Derived from Natural Camphor.” Synthesis, vol. 54, no. 21, Oct. 2021, pp. 4721-4726. https://doi.org/10.1055/a-1668-2075.