Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions
Publication type: Journal Article
Publication date: 2006-11-15
scimago Q1
wos Q2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
17129162
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Micellization in dilute solutions of diblock copolymers with a polyelectrolyte and a hydrophilic nonionic blocks and oppositely charged polyions is studied using mean-field theory. In aqueous solutions the micelle core consists of the polyelectrolyte complex (PEC) while the corona is formed by hydrophilic blocks of the block copolymers. Describing PEC as a globule in the framework of the Lifshitz [Zh. Eksp. Teor. Fiz. 55, 2408 (1968)] globule theory we calculate the surface tension of the micellar core/solvent interface as a function of the polyion degree of ionization, solvent quality, and concentration of low-molecular-mass salt. The equilibrium aggregation number of starlike micelles formed by block copolymers and homopolymers of opposite charge at stoichiometric mixture compositions is found as a function of the system parameters. It is shown that micelles disintegrate upon addition of salt.
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57
Total citations:
57
Citations from 2024:
9
(15.79%)
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GOST
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Kramarenko E. Yu., Khokhlov A. R., Reineker P. Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions // Journal of Chemical Physics. 2006. Vol. 125. No. 19. p. 194902.
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Kramarenko E. Yu., Khokhlov A. R., Reineker P. Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions // Journal of Chemical Physics. 2006. Vol. 125. No. 19. p. 194902.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1063/1.2387173
UR - https://doi.org/10.1063/1.2387173
TI - Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions
T2 - Journal of Chemical Physics
AU - Kramarenko, E Yu
AU - Khokhlov, A R
AU - Reineker, P.
PY - 2006
DA - 2006/11/15
PB - AIP Publishing
SP - 194902
IS - 19
VL - 125
PMID - 17129162
SN - 0021-9606
SN - 1089-7690
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_Kramarenko,
author = {E Yu Kramarenko and A R Khokhlov and P. Reineker},
title = {Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions},
journal = {Journal of Chemical Physics},
year = {2006},
volume = {125},
publisher = {AIP Publishing},
month = {nov},
url = {https://doi.org/10.1063/1.2387173},
number = {19},
pages = {194902},
doi = {10.1063/1.2387173}
}
Cite this
MLA
Copy
Kramarenko, E. Yu., et al. “Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions.” Journal of Chemical Physics, vol. 125, no. 19, Nov. 2006, p. 194902. https://doi.org/10.1063/1.2387173.
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