Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions
Тип публикации: Journal Article
Дата публикации: 2006-11-15
scimago Q1
wos Q2
white level БС2
SJR: 0.819
CiteScore: 5.3
Impact factor: 3.1
ISSN: 00219606, 10897690
PubMed ID:
17129162
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
Micellization in dilute solutions of diblock copolymers with a polyelectrolyte and a hydrophilic nonionic blocks and oppositely charged polyions is studied using mean-field theory. In aqueous solutions the micelle core consists of the polyelectrolyte complex (PEC) while the corona is formed by hydrophilic blocks of the block copolymers. Describing PEC as a globule in the framework of the Lifshitz [Zh. Eksp. Teor. Fiz. 55, 2408 (1968)] globule theory we calculate the surface tension of the micellar core/solvent interface as a function of the polyion degree of ionization, solvent quality, and concentration of low-molecular-mass salt. The equilibrium aggregation number of starlike micelles formed by block copolymers and homopolymers of opposite charge at stoichiometric mixture compositions is found as a function of the system parameters. It is shown that micelles disintegrate upon addition of salt.
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ГОСТ
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Kramarenko E. Yu., Khokhlov A. R., Reineker P. Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions // Journal of Chemical Physics. 2006. Vol. 125. No. 19. p. 194902.
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Kramarenko E. Yu., Khokhlov A. R., Reineker P. Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions // Journal of Chemical Physics. 2006. Vol. 125. No. 19. p. 194902.
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TY - JOUR
DO - 10.1063/1.2387173
UR - https://doi.org/10.1063/1.2387173
TI - Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions
T2 - Journal of Chemical Physics
AU - Kramarenko, E Yu
AU - Khokhlov, A R
AU - Reineker, P.
PY - 2006
DA - 2006/11/15
PB - AIP Publishing
SP - 194902
IS - 19
VL - 125
PMID - 17129162
SN - 0021-9606
SN - 1089-7690
ER -
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BibTex (до 50 авторов)
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@article{2006_Kramarenko,
author = {E Yu Kramarenko and A R Khokhlov and P. Reineker},
title = {Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions},
journal = {Journal of Chemical Physics},
year = {2006},
volume = {125},
publisher = {AIP Publishing},
month = {nov},
url = {https://doi.org/10.1063/1.2387173},
number = {19},
pages = {194902},
doi = {10.1063/1.2387173}
}
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MLA
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Kramarenko, E. Yu., et al. “Stoichiometric polyelectrolyte complexes of ionic block copolymers and oppositely charged polyions.” Journal of Chemical Physics, vol. 125, no. 19, Nov. 2006, p. 194902. https://doi.org/10.1063/1.2387173.
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