Open Access
Advanced Science, volume 9, issue 12, pages 2200217
High‐Quality Graphene Using Boudouard Reaction
Grebenko Artem
1, 2
,
Bubis Anton V
2, 3
,
Stolyarov Vasily S
1, 4, 5
,
Vyalikh Denis
6, 7
,
Makarova Anna A
8
,
Fedorov Alexander
9
,
Aitkulova Aisuluu
2
,
Alekseeva Alena A
2
,
Gilshtein Evgeniia
2, 10
,
Bedran Zakhar
1
,
Shmakov Alexander N.
11
,
Mozhchil Rais N
3, 12
,
Ionov Andrey M
3, 13
,
Laasonen Kari
14
,
Podzorov Vitaly
15
,
Nasibulin Albert G.
2, 14
15
Department of Physics Rutgers University Piscataway NJ 08854 USA
|
Publication type: Journal Article
Publication date: 2022-02-20
Medicine (miscellaneous)
General Chemical Engineering
General Physics and Astronomy
General Materials Science
General Engineering
Biochemistry, Genetics and Molecular Biology (miscellaneous)
Abstract
Following the game‐changing high‐pressure CO (HiPco) process that established the first facile route toward large‐scale production of single‐walled carbon nanotubes, CO synthesis of cm‐sized graphene crystals of ultra‐high purity grown during tens of minutes is proposed. The Boudouard reaction serves for the first time to produce individual monolayer structures on the surface of a metal catalyst, thereby providing a chemical vapor deposition technique free from molecular and atomic hydrogen as well as vacuum conditions. This approach facilitates inhibition of the graphene nucleation from the CO/CO2 mixture and maintains a high growth rate of graphene seeds reaching large‐scale monocrystals. Unique features of the Boudouard reaction coupled with CO‐driven catalyst engineering ensure not only suppression of the second layer growth but also provide a simple and reliable technique for surface cleaning. Aside from being a novel carbon source, carbon monoxide ensures peculiar modification of catalyst and in general opens avenues for breakthrough graphene‐catalyst composite production.
Citations by journals
|
1
|
|
|
Nanomaterials
|
Nanomaterials
1 publication, 9.09%
|
|
Molecules
|
Molecules
1 publication, 9.09%
|
|
Small Methods
|
Small Methods
1 publication, 9.09%
|
|
Nature Communications
|
Nature Communications
1 publication, 9.09%
|
|
AICHE Journal
|
AICHE Journal
1 publication, 9.09%
|
|
Advanced Materials Interfaces
|
Advanced Materials Interfaces
1 publication, 9.09%
|
|
Polymers
|
Polymers
1 publication, 9.09%
|
|
Advanced Science
|
Advanced Science
1 publication, 9.09%
|
|
Carbon
|
Carbon
1 publication, 9.09%
|
|
Physical Review Letters
|
Physical Review Letters
1 publication, 9.09%
|
|
High Temperature
|
High Temperature
1 publication, 9.09%
|
|
1
|
Citations by publishers
|
1
2
3
4
|
|
|
Wiley
|
Wiley
4 publications, 36.36%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 27.27%
|
|
Springer Nature
|
Springer Nature
1 publication, 9.09%
|
|
Elsevier
|
Elsevier
1 publication, 9.09%
|
|
American Physical Society (APS)
|
American Physical Society (APS)
1 publication, 9.09%
|
|
Pleiades Publishing
|
Pleiades Publishing
1 publication, 9.09%
|
|
1
2
3
4
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023,2024],"ids":[0,0,0],"codes":[0,0,0],"imageUrls":["","",""],"datasets":[{"label":"Citations number","data":[3,7,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":["27.27","63.64","9.09"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Nanomaterials","Molecules","Small Methods","Nature Communications","AICHE Journal","Advanced Materials Interfaces","Polymers","Advanced Science","Carbon","Physical Review Letters","High Temperature"],"ids":[10051,1770,4145,3231,5553,18764,11204,4130,37,4343,20842],"codes":[0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.09,9.09,9.09,9.09,9.09,9.09,9.09,9.09,9.09,9.09,9.09],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Wiley","Multidisciplinary Digital Publishing Institute (MDPI)","Springer Nature","Elsevier","American Physical Society (APS)","Pleiades Publishing"],"ids":[11,202,8,17,1539,101],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/nrK64iXHTzj43wMrfN1ZoUQ0vanswGzWPN45K3jA_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp"],"datasets":[{"label":"","data":[4,3,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[36.36,27.27,9.09,9.09,9.09,9.09],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Grebenko A. et al. High‐Quality Graphene Using Boudouard Reaction // Advanced Science. 2022. Vol. 9. No. 12. p. 2200217.
GOST all authors (up to 50)
Copy
Grebenko A., Krasnikov D. V., Bubis A. V., Stolyarov V. S., Vyalikh D., Makarova A. A., Fedorov A., Aitkulova A., Alekseeva A. A., Gilshtein E., Bedran Z., Shmakov A. N., Alyabyeva L., Mozhchil R. N., Ionov A. M., Gorshunov B. P., Laasonen K., Podzorov V., Nasibulin A. G. High‐Quality Graphene Using Boudouard Reaction // Advanced Science. 2022. Vol. 9. No. 12. p. 2200217.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/advs.202200217
UR - https://doi.org/10.1002%2Fadvs.202200217
TI - High‐Quality Graphene Using Boudouard Reaction
T2 - Advanced Science
AU - Stolyarov, Vasily S
AU - Makarova, Anna A
AU - Fedorov, Alexander
AU - Aitkulova, Aisuluu
AU - Gilshtein, Evgeniia
AU - Bedran, Zakhar
AU - Shmakov, Alexander N.
AU - Alyabyeva, Liudmila
AU - Mozhchil, Rais N
AU - Gorshunov, Boris P
AU - Podzorov, Vitaly
AU - Bubis, Anton V
AU - Ionov, Andrey M
AU - Laasonen, Kari
AU - Nasibulin, Albert G.
AU - Grebenko, Artem
AU - Krasnikov, Dmitry V.
AU - Vyalikh, Denis
AU - Alekseeva, Alena A
PY - 2022
DA - 2022/02/20 00:00:00
PB - Wiley
SP - 2200217
IS - 12
VL - 9
SN - 2198-3844
ER -
Cite this
BibTex
Copy
@article{2022_Grebenko,
author = {Vasily S Stolyarov and Anna A Makarova and Alexander Fedorov and Aisuluu Aitkulova and Evgeniia Gilshtein and Zakhar Bedran and Alexander N. Shmakov and Liudmila Alyabyeva and Rais N Mozhchil and Boris P Gorshunov and Vitaly Podzorov and Anton V Bubis and Andrey M Ionov and Kari Laasonen and Albert G. Nasibulin and Artem Grebenko and Dmitry V. Krasnikov and Denis Vyalikh and Alena A Alekseeva},
title = {High‐Quality Graphene Using Boudouard Reaction},
journal = {Advanced Science},
year = {2022},
volume = {9},
publisher = {Wiley},
month = {feb},
url = {https://doi.org/10.1002%2Fadvs.202200217},
number = {12},
pages = {2200217},
doi = {10.1002/advs.202200217}
}
Cite this
MLA
Copy
Grebenko, Artem, et al. “High‐Quality Graphene Using Boudouard Reaction.” Advanced Science, vol. 9, no. 12, Feb. 2022, p. 2200217. https://doi.org/10.1002%2Fadvs.202200217.