Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst
Alexey A. Tsygankov
1
,
Maria Makarova
1, 2
,
Oleg I Afanasyev
1
,
Alexey S Kashin
3
,
Alexander V. Naumkin
1, 4
,
Denis Chusov
1, 5
Publication type: Journal Article
Publication date: 2019-11-22
scimago Q1
wos Q2
SJR: 0.941
CiteScore: 6.1
Impact factor: 3.9
ISSN: 18673880, 18673899
Catalysis
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient method for preparation of secondary amides from primary amides and aldehydes using rhodium on carbon matrix as catalyst was developed. The method does not require any external hydrogen source and carbon monoxide is used as a reducing agent. The most active rhodium catalysts were characterized by BET, TEM and XPS techniques. Unexpectedly, it was found that heterogeneous rhodium on carbon matrix works as precatalyst for homogenous active species due to leaching of rhodium to the solution. Various secondary amides were synthesized and checked for antifungal activity. 4‐Methoxy‐N‐(4‐methoxybenzyl)benzamide demonstrated promising activity against Rhizoctonia Solani.
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11
Total citations:
11
Citations from 2025:
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(10%)
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Tsygankov A. A. et al. Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst // ChemCatChem. 2019. Vol. 12. No. 1. pp. 112-117.
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Tsygankov A. A., Makarova M., Afanasyev O. I., Kashin A. S., Naumkin A. V., Loginov D. A., Chusov D. Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst // ChemCatChem. 2019. Vol. 12. No. 1. pp. 112-117.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cctc.201901465
UR - https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201901465
TI - Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst
T2 - ChemCatChem
AU - Tsygankov, Alexey A.
AU - Makarova, Maria
AU - Afanasyev, Oleg I
AU - Kashin, Alexey S
AU - Naumkin, Alexander V.
AU - Loginov, Dmitry A.
AU - Chusov, Denis
PY - 2019
DA - 2019/11/22
PB - Wiley
SP - 112-117
IS - 1
VL - 12
SN - 1867-3880
SN - 1867-3899
ER -
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BibTex (up to 50 authors)
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@article{2019_Tsygankov,
author = {Alexey A. Tsygankov and Maria Makarova and Oleg I Afanasyev and Alexey S Kashin and Alexander V. Naumkin and Dmitry A. Loginov and Denis Chusov},
title = {Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst},
journal = {ChemCatChem},
year = {2019},
volume = {12},
publisher = {Wiley},
month = {nov},
url = {https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201901465},
number = {1},
pages = {112--117},
doi = {10.1002/cctc.201901465}
}
Cite this
MLA
Copy
Tsygankov, Alexey A., et al. “Reductive Amidation without an External Hydrogen Source Using Rhodium on Carbon Matrix as a Catalyst.” ChemCatChem, vol. 12, no. 1, Nov. 2019, pp. 112-117. https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cctc.201901465.