Chinese Journal of Chemistry, volume 40, issue 17, pages 2089-2105
Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization
Limarev Ilya P
1, 2
,
Zelinskii Genrikh E.
1, 2
,
Belova Svetlana A.
1, 2
,
Vologzhanina Anna V.
1
,
Lebed Ekaterina G
1, 2
,
Voloshin Yan Z.
1, 2
Publication type: Journal Article
Publication date: 2022-06-24
Journal:
Chinese Journal of Chemistry
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.4
ISSN: 1001604X, 16147065
General Chemistry
Abstract
Comprehensive Summary
General and straightforward synthetic strategy towards the iron(II) clathrochelates with functionalizing substituents in their apical capping and one of the three chelate ribbed fragments was developed. Their hexachloroclathrochelate precursors were prepared by the direct template condensation of dichloroglyoxime with a suitable boronic acid on the Fe2+ ion as a matrix and underwent a stepwise nucleophilic substitution with S2‐, N2‐ or O2‐bis‐nucleophiles, forming the alicyclic or aromatic N2‐, S2‐ or O2‐six‐membered fragments. Depending on the reaction conditions and precursor‐to‐dinucleophile molar ratios, iron(II) clathrochelates with one (S, O and N), two (S, O and N) or three (S and O) X2‐six‐membered ribbed substituent(s) were obtained. Their reactivity substantially decreases in a row: Cl6‐Cage > Cl4X2‐Cage (where X = S, O or, especially, N) > Cl2X4‐Cage (where X = S or O). The reactive monoribbed‐functionalized clathrochelates underwent further chemical transformations giving the target macrobicyclic complexes with terminal vector groups. As follows from the single crystal XRD data, their FeN6‐coordination polyhedra possess the geometry intermediate between a trigonal prism and a trigonal antiprism (φ = 21.3°—25.20°). Fe—N distances vary from 1.887(6) to 1.933(8) Å. Their 3D‐molecules, the hydrophobic–hydrophilic balance in which can be tuned using a ribbed functionalization, form in the crystals the intermolecular specific halogen bonds and/or hydrophobic interactions.
Citations by journals
|
1
|
|
|
Transition Metal Chemistry
|
Transition Metal Chemistry
1 publication, 33.33%
|
|
Dalton Transactions
|
Dalton Transactions
1 publication, 33.33%
|
|
Physical Chemistry Chemical Physics
|
Physical Chemistry Chemical Physics
1 publication, 33.33%
|
|
1
|
Citations by publishers
|
1
2
|
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 66.67%
|
|
Springer Nature
|
Springer Nature
1 publication, 33.33%
|
|
1
2
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2022,2023],"ids":[0,0],"codes":[0,0],"imageUrls":["",""],"datasets":[{"label":"Citations number","data":[1,2],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":["33.33","66.67"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Transition Metal Chemistry","Dalton Transactions","Physical Chemistry Chemical Physics"],"ids":[4341,8473,1773],"codes":[0,0,0],"imageUrls":["\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp"],"datasets":[{"label":"","data":[1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6"],"percentage":[33.33,33.33,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Royal Society of Chemistry (RSC)","Springer Nature"],"ids":[123,8],"codes":[0,0],"imageUrls":["\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp"],"datasets":[{"label":"","data":[2,1],"backgroundColor":["#3B82F6","#3B82F6"],"percentage":[66.67,33.33],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Limarev I. P. et al. Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization // Chinese Journal of Chemistry. 2022. Vol. 40. No. 17. pp. 2089-2105.
GOST all authors (up to 50)
Copy
Limarev I. P., Zelinskii G. E., Belova S. A., Dorovatovskii P. V., Vologzhanina A. V., Lebed E. G., Voloshin Y. Z. Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization // Chinese Journal of Chemistry. 2022. Vol. 40. No. 17. pp. 2089-2105.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1002/cjoc.202200191
UR - https://doi.org/10.1002%2Fcjoc.202200191
TI - Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization
T2 - Chinese Journal of Chemistry
AU - Limarev, Ilya P
AU - Zelinskii, Genrikh E.
AU - Belova, Svetlana A.
AU - Dorovatovskii, Pavel V.
AU - Vologzhanina, Anna V.
AU - Lebed, Ekaterina G
AU - Voloshin, Yan Z.
PY - 2022
DA - 2022/06/24 00:00:00
PB - Wiley
SP - 2089-2105
IS - 17
VL - 40
SN - 1001-604X
SN - 1614-7065
ER -
Cite this
BibTex
Copy
@article{2022_Limarev,
author = {Ilya P Limarev and Genrikh E. Zelinskii and Svetlana A. Belova and Pavel V. Dorovatovskii and Anna V. Vologzhanina and Ekaterina G Lebed and Yan Z. Voloshin},
title = {Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization},
journal = {Chinese Journal of Chemistry},
year = {2022},
volume = {40},
publisher = {Wiley},
month = {jun},
url = {https://doi.org/10.1002%2Fcjoc.202200191},
number = {17},
pages = {2089--2105},
doi = {10.1002/cjoc.202200191}
}
Cite this
MLA
Copy
Limarev, Ilya P., et al. “Monoribbed‐Functionalized Macrobicyclic Iron( II ) Complexes Decorated with Terminal Reactive and Vector Groups: Synthetic Strategy, Chemical Transformations and Structural Characterization.” Chinese Journal of Chemistry, vol. 40, no. 17, Jun. 2022, pp. 2089-2105. https://doi.org/10.1002%2Fcjoc.202200191.
Profiles