X-ray photoelectron spectra and electron structure of polynuclear cobalt complexes
Publication type: Journal Article
Publication date: 2007-05-01
scimago Q2
wos Q3
SJR: 0.601
CiteScore: 3.6
Impact factor: 1.5
ISSN: 03682048, 18732526
Electronic, Optical and Magnetic Materials
Physical and Theoretical Chemistry
Spectroscopy
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Radiation
Abstract
Abstract XPS has been used to study the electronic structure of cobalt trimethylacetate complexes. The compounds were high-spin paramagnetic mono- and polynuclear Co(II) complexes, diamagnetic Co(III) complex and mixed polynuclear di-macroheterocyclic Co(II)/Co(III) one. The Co 2p1/2–Co 2p3/2 spin–orbit splitting (ΔE1) was close to 16, 15 and 15.3 eV, respectively. An intense satellite structure was most noticeable for the Co 2p and Co 3p lines in the case of paramagnetic compounds, but not for the diamagnetic complex. The XPS data are in good agreement with the X-ray structure analysis (XSA).
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114
Total citations:
114
Citations from 2024:
36
(31%)
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Ivanova T. et al. X-ray photoelectron spectra and electron structure of polynuclear cobalt complexes // Journal of Electron Spectroscopy and Related Phenomena. 2007. Vol. 156-158. pp. 200-203.
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Ivanova T., Naumkin A. V., Sidorov A., Eremenko I. L., Kiskin M. A. X-ray photoelectron spectra and electron structure of polynuclear cobalt complexes // Journal of Electron Spectroscopy and Related Phenomena. 2007. Vol. 156-158. pp. 200-203.
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TY - JOUR
DO - 10.1016/j.elspec.2006.12.005
UR - https://doi.org/10.1016/j.elspec.2006.12.005
TI - X-ray photoelectron spectra and electron structure of polynuclear cobalt complexes
T2 - Journal of Electron Spectroscopy and Related Phenomena
AU - Ivanova, T.M.
AU - Naumkin, Alexander V.
AU - Sidorov, A.V
AU - Eremenko, Igor L.
AU - Kiskin, Mikhail A.
PY - 2007
DA - 2007/05/01
PB - Elsevier
SP - 200-203
VL - 156-158
SN - 0368-2048
SN - 1873-2526
ER -
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@article{2007_Ivanova,
author = {T.M. Ivanova and Alexander V. Naumkin and A.V Sidorov and Igor L. Eremenko and Mikhail A. Kiskin},
title = {X-ray photoelectron spectra and electron structure of polynuclear cobalt complexes},
journal = {Journal of Electron Spectroscopy and Related Phenomena},
year = {2007},
volume = {156-158},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/j.elspec.2006.12.005},
pages = {200--203},
doi = {10.1016/j.elspec.2006.12.005}
}