Mechanical properties and antibacterial activities of novel starch-based composite films incorporated with salicylic acid

To control food contamination and meet the growing demand for high quality food, a novel and excellent starch composite film as packing material with optimized physical, mechanical properties and antimicrobial activity was produced in this paper. Starch-based composite films incorporated with salicylic acid (SA) and waxy maize starch nanoparticles/κ-carrageenan (WMSNs/KC) were used to achieve antimicrobial activity and improve the mechanical properties. WMSNs were fabricated through enzymolysis and recrystallisation method, followed by individually adding KC to form WMSNs/KC by self-assembly, and used as a nanofiller and stabilizer to be incorporated into hydroxypropyl tapioca starch-based films at a concentration of 0–9%. Characterization of macromorphology and scanning electron microscope indicated the starch composite films with WMSNs/KC were smooth, uniform, and transparent. X-ray diffraction pattern and Thermogravimetric analysis also showed strong interactions such as hydrogen bond formation among films, WMSNs/KC and SA. Compared with the pure starch-based films, the composite films reinforced by the addition of WMSNs/KC significantly increased the tensile strength, water vapor barrier and thermal stability, while the transparency and elongation at break decreased slightly. Moreover, the starch composite films showed excellent antimicrobial activity for three typical undesired microorganisms in foods, Escherichia coli , Staphylococcus aureus , and Bacillus subtilis. • Novel antibacterial and biodegradable starch composite films were proposed. • Mechanical properties, water vapor barrier of our films were reinforced by WMSNs/KC. • For the first time, starch-based films with SA achieved antimicrobial activity. • Substantial bacteriostatic effect was obtained in yogurt in contact with our films. • This product was nontoxic, edible and could extend the shelf life of food.