Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9
Publication type: Journal Article
Publication date: 2018-06-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A series of 12-vertex closo-cobaltacarboranes 1,2-Rʹ2-3-(C5R5)-3,1,2-CoC2B9H9 (1a: R = Rʹ = H; 1b: R = Me, Rʹ = H; 2a: R = H, Rʹ = Me; 2b: R = Rʹ = Me) were synthesized by reactions of the carbonyl cobalt complexes (C5R5)Co(CO)I2 with Tl[Tl(η-7,8-Rʹ2-7,8-C2B9H9)]. The reaction of CpCo(CO)I2 with Tl[Tl(η-7,8-Me2-7,8-C2B9H9)] is accompanied by side formation of the novel charge-compensated nido-carborane 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9 (3) in 19% yield. The structures of 2a,b and 3 were determined by X-ray diffraction.
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Kuvshinova S. S. et al. Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9 // Journal of Organometallic Chemistry. 2018. Vol. 865. pp. 109-113.
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Kuvshinova S. S., Nelyubina Y. V., Smol’yakov A. F., Kosenko I., Barakovskaya I. G., Loginov D. A. Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9 // Journal of Organometallic Chemistry. 2018. Vol. 865. pp. 109-113.
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TY - JOUR
DO - 10.1016/j.jorganchem.2018.01.045
UR - https://linkinghub.elsevier.com/retrieve/pii/S0022328X18300603
TI - Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9
T2 - Journal of Organometallic Chemistry
AU - Kuvshinova, Sofya S
AU - Nelyubina, Yulia V.
AU - Smol’yakov, Alexander F.
AU - Kosenko, I.
AU - Barakovskaya, Irina G
AU - Loginov, Dmitry A.
PY - 2018
DA - 2018/06/01
PB - Elsevier
SP - 109-113
VL - 865
SN - 0022-328X
SN - 1872-8561
ER -
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@article{2018_Kuvshinova,
author = {Sofya S Kuvshinova and Yulia V. Nelyubina and Alexander F. Smol’yakov and I. Kosenko and Irina G Barakovskaya and Dmitry A. Loginov},
title = {Usage of (C5R5)Co(CO)I2 (R = H, Me) for the synthesis of 12-vertex closo-cobaltacarboranes. Unexpected formation of 10-{CpCo(C5H4)}-7,8-Me2-7,8-nido-C2B9H9},
journal = {Journal of Organometallic Chemistry},
year = {2018},
volume = {865},
publisher = {Elsevier},
month = {jun},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0022328X18300603},
pages = {109--113},
doi = {10.1016/j.jorganchem.2018.01.045}
}