ACS Catalysis, volume 11, issue 21, pages 13077-13084
Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran
Publication type: Journal Article
Publication date: 2021-10-13
General Chemistry
Catalysis
Abstract
We demonstrate that well-known transition metal catalysts can be transformed into high-performance versions by the simple use of a fluoride anion source. In situ fluoride-activated catalysts are highly active catalytic species. The isolation may lead to degradation of the species or a decrease in catalytic activity. Fluoride activation of known, relatively simple catalysts resulted in the development of one of the most efficient catalytic systems for the asymmetric cyanation of aldehydes, asymmetric Michael addition, and synthesis of cyclic carbonates. Furthermore, the fluoride-assisted reductive opening of tetrahydrofuran (THF) with amines was developed. We believe that the proposed approach can find broad applications in the enhancement of known catalytic processes and in the design of new ones.
Citations by journals
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Journal of Organic Chemistry
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2 publications, 14.29%
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Citations by publishers
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6
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American Chemical Society (ACS)
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American Chemical Society (ACS)
6 publications, 42.86%
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Elsevier
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4 publications, 28.57%
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Wiley
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Wiley
3 publications, 21.43%
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Pleiades Publishing
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Pleiades Publishing
1 publication, 7.14%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Tsygankov A. A., Chusov D. Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran // ACS Catalysis. 2021. Vol. 11. No. 21. pp. 13077-13084.
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Tsygankov A. A., Chusov D. Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran // ACS Catalysis. 2021. Vol. 11. No. 21. pp. 13077-13084.
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TY - JOUR
DO - 10.1021/acscatal.1c03785
UR - https://doi.org/10.1021%2Facscatal.1c03785
TI - Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran
T2 - ACS Catalysis
AU - Tsygankov, Alexey A.
AU - Chusov, Denis
PY - 2021
DA - 2021/10/13 00:00:00
PB - American Chemical Society (ACS)
SP - 13077-13084
IS - 21
VL - 11
SN - 2155-5435
ER -
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@article{2021_Tsygankov,
author = {Alexey A. Tsygankov and Denis Chusov},
title = {Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran},
journal = {ACS Catalysis},
year = {2021},
volume = {11},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021%2Facscatal.1c03785},
number = {21},
pages = {13077--13084},
doi = {10.1021/acscatal.1c03785}
}
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Tsygankov, Alexey A., and Denis Chusov. “Straightforward Access to High-Performance Organometallic Catalysts by Fluoride Activation: Proof of Principle on Asymmetric Cyanation, Asymmetric Michael Addition, CO2 Addition to Epoxide, and Reductive Alkylation of Amines by Tetrahydrofuran.” ACS Catalysis, vol. 11, no. 21, Oct. 2021, pp. 13077-13084. https://doi.org/10.1021%2Facscatal.1c03785.
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