Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
4
Ufa Oil Institute, Kosmonavtov Str., 1, Ufa 450062, Russian Federation
|
Publication type: Journal Article
Publication date: 2018-07-24
scimago Q2
wos Q1
SJR: 0.676
CiteScore: 5.1
Impact factor: 2.9
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
An efficient protocol for synthesis of indenyl rhodium complexes with arene ligands has been developed. The hexafluoroantimonate salts [(η5-indenyl)Rh(arene)](SbF6)2 (arene = benzene (2a), o-xylene (2b), mesitylene (2c), durene (2d), hexamethylbenzene (2e), and [2.2]paracyclophane (2g)) were obtained by iodide abstraction from [(η5-indenyl)RhI2]n (1) with AgSbF6 in the presence of benzene and its derivatives. The procedure is also suitable for the synthesis of the dirhodium arene complex [(μ-η:η′-1,3-dimesitylpropane){Rh(η5-indenyl)}2](SbF6)4 (3) starting from 1,3-dimesitylpropane. The structures of [2e](SbF6)2, [2g](SbF6)2, and [3](SbF6)4 were determined by X-ray diffraction. The last species has a sterically unfavorable conformation, in which the bridgehead carbon atoms of the indenyl ligand are arranged close to the propane linker between two mesitylene moieties. Experimental and DFT calculation data revealed that the benzene ligand in 2a is more labile than that in the related cyclopentadienyl complex...
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Total citations:
29
Citations from 2024:
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(24.13%)
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Kharitonov V. B. et al. Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination // Organometallics. 2018. Vol. 37. No. 15. pp. 2553-2562.
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Kharitonov V. B., Makarova M., Arsenov M. A., Nelyubina Y. V., Chusova O., Peregudov A. S., Zlotskii S. S., Chusov D., Loginov D. A. Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination // Organometallics. 2018. Vol. 37. No. 15. pp. 2553-2562.
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TY - JOUR
DO - 10.1021/acs.organomet.8b00311
UR - https://doi.org/10.1021/acs.organomet.8b00311
TI - Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination
T2 - Organometallics
AU - Kharitonov, Vladimir B.
AU - Makarova, Maria
AU - Arsenov, Mikhail A
AU - Nelyubina, Yulia V.
AU - Chusova, Olga
AU - Peregudov, A. S.
AU - Zlotskii, Semen S
AU - Chusov, Denis
AU - Loginov, Dmitry A.
PY - 2018
DA - 2018/07/24
PB - American Chemical Society (ACS)
SP - 2553-2562
IS - 15
VL - 37
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2018_Kharitonov,
author = {Vladimir B. Kharitonov and Maria Makarova and Mikhail A Arsenov and Yulia V. Nelyubina and Olga Chusova and A. S. Peregudov and Semen S Zlotskii and Denis Chusov and Dmitry A. Loginov},
title = {Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination},
journal = {Organometallics},
year = {2018},
volume = {37},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acs.organomet.8b00311},
number = {15},
pages = {2553--2562},
doi = {10.1021/acs.organomet.8b00311}
}
Cite this
MLA
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Kharitonov, Vladimir B., et al. “Indenyl Rhodium Complexes with Arene Ligands: Synthesis and Application for Reductive Amination.” Organometallics, vol. 37, no. 15, Jul. 2018, pp. 2553-2562. https://doi.org/10.1021/acs.organomet.8b00311.