The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis
César A. Urbina-Blanco
1
,
Albert Poater
2
,
T. Lébl
1
,
Simone Manzini
1
,
Luigi Maria Cavallo
3, 4
,
Publication type: Journal Article
Publication date: 2013-04-25
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
23617632
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Olefin metathesis is a powerful tool for the formation of carbon-carbon double bonds. Several families of well-defined ruthenium (Ru) catalysts have been developed during the past 20 years; however, the reaction mechanism for all such complexes was assumed to be the same. In the present study, the initiation mechanism of Ru-indenylidene complexes was examined and compared with that of benzylidene counterparts. It was discovered that not all indenylidene complexes followed the same mechanism, highlighting the importance of steric and electronic properties of so-called spectator ligands, and that there is no single mechanism for the Ru-based olefin metathesis reaction. The experimental findings are supported quantitatively by DFT calculations.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
12
|
|
|
Organometallics
12 publications, 11.76%
|
|
|
Beilstein Journal of Organic Chemistry
5 publications, 4.9%
|
|
|
Chemistry - A European Journal
5 publications, 4.9%
|
|
|
Journal of the American Chemical Society
5 publications, 4.9%
|
|
|
Chemical Communications
5 publications, 4.9%
|
|
|
Dalton Transactions
5 publications, 4.9%
|
|
|
Catalysis Science and Technology
4 publications, 3.92%
|
|
|
Catalysts
3 publications, 2.94%
|
|
|
Molecular Catalysis
3 publications, 2.94%
|
|
|
Journal of Organometallic Chemistry
3 publications, 2.94%
|
|
|
Applied Organometallic Chemistry
3 publications, 2.94%
|
|
|
Journal of Computational Chemistry
3 publications, 2.94%
|
|
|
ACS Catalysis
3 publications, 2.94%
|
|
|
Coordination Chemistry Reviews
2 publications, 1.96%
|
|
|
Angewandte Chemie
2 publications, 1.96%
|
|
|
Angewandte Chemie - International Edition
2 publications, 1.96%
|
|
|
European Journal of Organic Chemistry
2 publications, 1.96%
|
|
|
Journal of Physical Chemistry A
2 publications, 1.96%
|
|
|
RSC Advances
2 publications, 1.96%
|
|
|
Molecules
1 publication, 0.98%
|
|
|
Chemistry of Heterocyclic Compounds
1 publication, 0.98%
|
|
|
Journal of Molecular Modeling
1 publication, 0.98%
|
|
|
Theoretical Chemistry Accounts
1 publication, 0.98%
|
|
|
Monatshefte fur Chemie
1 publication, 0.98%
|
|
|
Catalysis Today
1 publication, 0.98%
|
|
|
Tetrahedron Letters
1 publication, 0.98%
|
|
|
Catalysis Communications
1 publication, 0.98%
|
|
|
Polyhedron
1 publication, 0.98%
|
|
|
Journal of Molecular Catalysis A Chemical
1 publication, 0.98%
|
|
|
2
4
6
8
10
12
|
Publishers
|
5
10
15
20
25
|
|
|
Wiley
25 publications, 24.51%
|
|
|
American Chemical Society (ACS)
25 publications, 24.51%
|
|
|
Royal Society of Chemistry (RSC)
19 publications, 18.63%
|
|
|
Elsevier
18 publications, 17.65%
|
|
|
Beilstein-Institut
5 publications, 4.9%
|
|
|
MDPI
4 publications, 3.92%
|
|
|
Springer Nature
4 publications, 3.92%
|
|
|
Taylor & Francis
1 publication, 0.98%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.98%
|
|
|
5
10
15
20
25
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
102
Total citations:
102
Citations from 2024:
8
(7.84%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Urbina-Blanco C. A. et al. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
GOST all authors (up to 50)
Copy
Urbina-Blanco C. A., Poater A., Lébl T., Manzini S., Slawin A. M. Z., Cavallo L. M., Nolan S. P. The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis // Journal of the American Chemical Society. 2013. Vol. 135. No. 18. pp. 7073-7079.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja402700p
UR - https://doi.org/10.1021/ja402700p
TI - The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis
T2 - Journal of the American Chemical Society
AU - Urbina-Blanco, César A.
AU - Poater, Albert
AU - Lébl, T.
AU - Manzini, Simone
AU - Slawin, Alexandra M. Z.
AU - Cavallo, Luigi Maria
AU - Nolan, Steven P.
PY - 2013
DA - 2013/04/25
PB - American Chemical Society (ACS)
SP - 7073-7079
IS - 18
VL - 135
PMID - 23617632
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2013_Urbina-Blanco,
author = {César A. Urbina-Blanco and Albert Poater and T. Lébl and Simone Manzini and Alexandra M. Z. Slawin and Luigi Maria Cavallo and Steven P. Nolan},
title = {The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis},
journal = {Journal of the American Chemical Society},
year = {2013},
volume = {135},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja402700p},
number = {18},
pages = {7073--7079},
doi = {10.1021/ja402700p}
}
Cite this
MLA
Copy
Urbina-Blanco, César A., et al. “The Activation Mechanism of Ru–Indenylidene Complexes in Olefin Metathesis.” Journal of the American Chemical Society, vol. 135, no. 18, Apr. 2013, pp. 7073-7079. https://doi.org/10.1021/ja402700p.