Organometallics, volume 30, issue 6, pages 1607-1615
Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes
Publication type: Journal Article
Publication date: 2011-02-23
Journal:
Organometallics
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 02767333, 15206041
Organic Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
cis-Dichloro−trans-dichloro isomerization was studied in sulfur-chelated ruthenium benzylidenes. The effect of solvents and additives on the isomerization process was analyzed. Notably, π-acid ligand molecules, dichloromethane, and polar solvents were found to significantly accelerate the isomerization rate. As expected, the cis−trans isomer equilibria had a strong effect on the olefin metathesis reactivity; the bulkier cis-dichloro catalysts, which show a larger amount of trans isomer in the equilibrium, were more reactive than their less bulky counterparts. This tendency was generally reversed in the isolated trans isomer series, where both steric factors and faster isomerization play a role in dictating the olefin metathesis reactivity. A better understanding of the trans−cis isomerization and the mechanism that governs reactivity in strongly chelated cis-dichloro ruthenium benzylidenes was obtained.
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Aharoni A. et al. Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes // Organometallics. 2011. Vol. 30. No. 6. pp. 1607-1615.
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Aharoni A., Vidavsky Y., Diesendruck C. E., Ben-Asuly A., Goldberg I., Lemcoff N. G. Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes // Organometallics. 2011. Vol. 30. No. 6. pp. 1607-1615.
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TY - JOUR
DO - 10.1021/om1011402
UR - https://doi.org/10.1021/om1011402
TI - Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes
T2 - Organometallics
AU - Aharoni, Anna
AU - Ben-Asuly, Amos
AU - Vidavsky, Yuval
AU - Diesendruck, Charles E.
AU - Goldberg, Israel
AU - Lemcoff, N Gabriel
PY - 2011
DA - 2011/02/23 00:00:00
PB - American Chemical Society (ACS)
SP - 1607-1615
IS - 6
VL - 30
SN - 0276-7333
SN - 1520-6041
ER -
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@article{2011_Aharoni,
author = {Anna Aharoni and Amos Ben-Asuly and Yuval Vidavsky and Charles E. Diesendruck and Israel Goldberg and N Gabriel Lemcoff},
title = {Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes},
journal = {Organometallics},
year = {2011},
volume = {30},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/om1011402},
number = {6},
pages = {1607--1615},
doi = {10.1021/om1011402}
}
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MLA
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Aharoni, Anna, et al. “Ligand Isomerization in Sulfur-Chelated Ruthenium Benzylidenes.” Organometallics, vol. 30, no. 6, Feb. 2011, pp. 1607-1615. https://doi.org/10.1021/om1011402.